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Comparison on Thermal Runaway and Critical Characteristics of Cylindrical Lithium-Ion Batteries: A Review
https://orcid.org/0000-0001-9069-5739
https://orcid.org/0000-0003-4452-7229
The thermal hazard results of commercial cylindrical lithium-ion batteries (LIBs) of different sizes from international laboratories are reviewed and discussed. The four types discussed encompass 14500, 18650, 21700, and 26650 ones. Characteristic data from the calorimeter include onset temperature, critical temperature, maximum temperature, maximum self-heat rate, enthalpy change, and quantity of noncondensable gases. By integrating thermal hazard data, a box-plot was established and hazard ranking was clearly evaluated as 21700 > 18650 non-LiFePO4 (LFP) ≫ 26650 LFP > 14500 non-LFP > 18650 LFP > 14500 LFP. Among all types of cylindrical lithium-ion batteries, the 21700 exhibits the worst consequence, which is attributed to the adoption of high energy density LiNi0.8Co0.15Al0.05O2 (NCA) and LiNi x Mn y Co z O2 (NMC) cathode materials. It was found that the critical temperature T cr and maximum temperature broadly scattered; besides, most of the maximum self-heat rate (dT/dt) and pressure data were absent in literature. Definitions of onset temperature, critical temperature, trigger temperature, and possible heat sources to stimulate the severe thermal runaway were collected and found to be unimaginably divergent. A thermal analysis database was established to classify critical temperatures into high T cr (above 180 °C), low T cr (130–180 °C), and no T cr. The low T cr inducement is speculated to be caused by gas shock or electron breakdown after the separator melted, while the intrinsic characteristics of T cr require further investigation. Thermal runaway features of cylindrical LIBs can be concisely classified as lowest T onset of 88.0 °C (21700 NMC) vs highest T onset of 220.0 °C (18650 LFP), highest (dT/dt)max of 64536.0 °C min–1 (21700 NCA) vs lowest (dT/dt)max of 3.0 °C min–1 (18650 LFP), highest T max of 1257.9 °C (21700 NCA) vs lowest T max of 243.2 °C (18650 LFP), highest Δn of 314.0 mmol (18650 NCA) vs lowest Δn of 23.3 mmol (14500 LFP), lowest T cr of 145.5 °C (21700 NCA) vs (no T cr) (14500 and 18650 LFP), and highest ΔH of 70.5 kJ (21700 NCA) vs lowest ΔH of 0.8 kJ (14500 LFP). In this work, the present research is reviewed in detail and future perspectives are proposed. This review on the critical characteristics of cylindrical batteries under thermal failure and thermal abuse provides a reference for solving intrinsic safety issues for lithium-ion batteries of the next generation.
Comparison on Thermal Runaway and Critical Characteristics of Cylindrical Lithium-Ion Batteries: A Review
https://orcid.org/0000-0001-9069-5739
https://orcid.org/0000-0003-4452-7229
The thermal hazard results of commercial cylindrical lithium-ion batteries (LIBs) of different sizes from international laboratories are reviewed and discussed. The four types discussed encompass 14500, 18650, 21700, and 26650 ones. Characteristic data from the calorimeter include onset temperature, critical temperature, maximum temperature, maximum self-heat rate, enthalpy change, and quantity of noncondensable gases. By integrating thermal hazard data, a box-plot was established and hazard ranking was clearly evaluated as 21700 > 18650 non-LiFePO4 (LFP) ≫ 26650 LFP > 14500 non-LFP > 18650 LFP > 14500 LFP. Among all types of cylindrical lithium-ion batteries, the 21700 exhibits the worst consequence, which is attributed to the adoption of high energy density LiNi0.8Co0.15Al0.05O2 (NCA) and LiNi x Mn y Co z O2 (NMC) cathode materials. It was found that the critical temperature T cr and maximum temperature broadly scattered; besides, most of the maximum self-heat rate (dT/dt) and pressure data were absent in literature. Definitions of onset temperature, critical temperature, trigger temperature, and possible heat sources to stimulate the severe thermal runaway were collected and found to be unimaginably divergent. A thermal analysis database was established to classify critical temperatures into high T cr (above 180 °C), low T cr (130–180 °C), and no T cr. The low T cr inducement is speculated to be caused by gas shock or electron breakdown after the separator melted, while the intrinsic characteristics of T cr require further investigation. Thermal runaway features of cylindrical LIBs can be concisely classified as lowest T onset of 88.0 °C (21700 NMC) vs highest T onset of 220.0 °C (18650 LFP), highest (dT/dt)max of 64536.0 °C min–1 (21700 NCA) vs lowest (dT/dt)max of 3.0 °C min–1 (18650 LFP), highest T max of 1257.9 °C (21700 NCA) vs lowest T max of 243.2 °C (18650 LFP), highest Δn of 314.0 mmol (18650 NCA) vs lowest Δn of 23.3 mmol (14500 LFP), lowest T cr of 145.5 °C (21700 NCA) vs (no T cr) (14500 and 18650 LFP), and highest ΔH of 70.5 kJ (21700 NCA) vs lowest ΔH of 0.8 kJ (14500 LFP). In this work, the present research is reviewed in detail and future perspectives are proposed. This review on the critical characteristics of cylindrical batteries under thermal failure and thermal abuse provides a reference for solving intrinsic safety issues for lithium-ion batteries of the next generation.
Comparison on Thermal Runaway and Critical Characteristics of Cylindrical Lithium-Ion Batteries: A Review
https://orcid.org/0000-0001-9069-5739
https://orcid.org/0000-0003-4452-7229
The thermal hazard results of commercial cylindrical lithium-ion batteries (LIBs) of different sizes from international laboratories are reviewed and discussed. The four types discussed encompass 14500, 18650, 21700, and 26650 ones. Characteristic data from the calorimeter include onset temperature, critical temperature, maximum temperature, maximum self-heat rate, enthalpy change, and quantity of noncondensable gases. By integrating thermal hazard data, a box-plot was established and hazard ranking was clearly evaluated as 21700 > 18650 non-LiFePO4 (LFP) ≫ 26650 LFP > 14500 non-LFP > 18650 LFP > 14500 LFP. Among all types of cylindrical lithium-ion batteries, the 21700 exhibits the worst consequence, which is attributed to the adoption of high energy density LiNi0.8Co0.15Al0.05O2 (NCA) and LiNi x Mn y Co z O2 (NMC) cathode materials. It was found that the critical temperature T cr and maximum temperature broadly scattered; besides, most of the maximum self-heat rate (dT/dt) and pressure data were absent in literature. Definitions of onset temperature, critical temperature, trigger temperature, and possible heat sources to stimulate the severe thermal runaway were collected and found to be unimaginably divergent. A thermal analysis database was established to classify critical temperatures into high T cr (above 180 °C), low T cr (130–180 °C), and no T cr. The low T cr inducement is speculated to be caused by gas shock or electron breakdown after the separator melted, while the intrinsic characteristics of T cr require further investigation. Thermal runaway features of cylindrical LIBs can be concisely classified as lowest T onset of 88.0 °C (21700 NMC) vs highest T onset of 220.0 °C (18650 LFP), highest (dT/dt)max of 64536.0 °C min–1 (21700 NCA) vs lowest (dT/dt)max of 3.0 °C min–1 (18650 LFP), highest T max of 1257.9 °C (21700 NCA) vs lowest T max of 243.2 °C (18650 LFP), highest Δn of 314.0 mmol (18650 NCA) vs lowest Δn of 23.3 mmol (14500 LFP), lowest T cr of 145.5 °C (21700 NCA) vs (no T cr) (14500 and 18650 LFP), and highest ΔH of 70.5 kJ (21700 NCA) vs lowest ΔH of 0.8 kJ (14500 LFP). In this work, the present research is reviewed in detail and future perspectives are proposed. This review on the critical characteristics of cylindrical batteries under thermal failure and thermal abuse provides a reference for solving intrinsic safety issues for lithium-ion batteries of the next generation.
Comparison on Thermal Runaway and Critical Characteristics of Cylindrical Lithium-Ion Batteries: A Review
Li, Wei (Autor:in) / Wang, Jiasheng (Autor:in) / Sun, Chunfeng (Autor:in) / Fan, Xiaoping (Autor:in) / Gong, Lingzhu (Autor:in) / Huang, Jiale (Autor:in) / Wu, Jian-heng (Autor:in) / Yu, Gending (Autor:in) / Chen, Rongguo (Autor:in) / Li, Jingling (Autor:in)
ACS Chemical Health & Safety ; 32 ; 133-156
24.03.2025
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
Self-reactive rating of thermal runaway hazards on 18650 lithium-ion batteries
| Tema Archiv | 2011
| Wiley | 2018
| American Chemical Society | 2022