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Adsorption-Induced Breathing Transitions in Metal-Organic Frameworks
Breathing transitions represent recently discovered adsorption-induced structural transformations between large-pore and narrow-pore conformations in bistable metal-organic frameworks, such as MIL-53. We present a multiscale physical mechanism of the dynamics of breathing transitions. We show that due to interplay between host framework elasticity and guest molecule adsorption, these transformations on the crystal level occur via layer-by-layer shear.
Adsorption-Induced Breathing Transitions in Metal-Organic Frameworks
Breathing transitions represent recently discovered adsorption-induced structural transformations between large-pore and narrow-pore conformations in bistable metal-organic frameworks, such as MIL-53. We present a multiscale physical mechanism of the dynamics of breathing transitions. We show that due to interplay between host framework elasticity and guest molecule adsorption, these transformations on the crystal level occur via layer-by-layer shear.
Adsorption-Induced Breathing Transitions in Metal-Organic Frameworks
Fuchs, Alain H. (Autor:in) / Coudert, François-Xavier (Autor:in) / Triguero, Carles (Autor:in) / Boutin, Anne (Autor:in) / Neimark, Alexander V. (Autor:in)
Fifth Biot Conference on Poromechanics ; 2013 ; Vienna, Austria
Poromechanics V ; 626-631
18.06.2013
Aufsatz (Konferenz)
Elektronische Ressource
Englisch
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