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Phase behavior in copolymer blends of polystyrene and poly(o-chlorostyrene-co-p-chlorostyrene)
The miscibility of random copolymers of o-chlorostyrene and p-chlorostyrene [P(oClS-pClS)] with polystyrene (PS) has been studied by differential scanning calorimetry (DSC). A miscibility “window” was found, extending in copolymer composition from about 68 to 98 mole % o-chlorostyrene at a temperature of 150 °C. The maximum in the miscibility window occurred at approximately 170 °C and a composition of 83 mole % o-chlorostyrene. This result differs only slightly from theoretical predictions based on interaction parameters previously calculated from miscibility behavior in blends of poly(2,6-dimethyl-1,4-phenylene oxide) with P(oClS-pClS), poly(styrene-co-o-chlorostyrene) and poly(styrene-co-p-chlorostyrene). The implication of this result for the numerical values of the six interaction parameters required to describe these blends is discussed.
Phase behavior in copolymer blends of polystyrene and poly(o-chlorostyrene-co-p-chlorostyrene)
The miscibility of random copolymers of o-chlorostyrene and p-chlorostyrene [P(oClS-pClS)] with polystyrene (PS) has been studied by differential scanning calorimetry (DSC). A miscibility “window” was found, extending in copolymer composition from about 68 to 98 mole % o-chlorostyrene at a temperature of 150 °C. The maximum in the miscibility window occurred at approximately 170 °C and a composition of 83 mole % o-chlorostyrene. This result differs only slightly from theoretical predictions based on interaction parameters previously calculated from miscibility behavior in blends of poly(2,6-dimethyl-1,4-phenylene oxide) with P(oClS-pClS), poly(styrene-co-o-chlorostyrene) and poly(styrene-co-p-chlorostyrene). The implication of this result for the numerical values of the six interaction parameters required to describe these blends is discussed.
Phase behavior in copolymer blends of polystyrene and poly(o-chlorostyrene-co-p-chlorostyrene)
ten Brinke, Gerrit (Autor:in) / Rubinstein, Ellen (Autor:in) / Karasz, Frank E. (Autor:in) / MacKnight, W. J. (Autor:in) / Vukovic, R. (Autor:in)
01.01.1984
ten Brinke , G , Rubinstein , E , Karasz , F E , MacKnight , W J & Vukovic , R 1984 , ' Phase behavior in copolymer blends of polystyrene and poly(o-chlorostyrene-co-p-chlorostyrene) ' , Journal of Applied Physics , vol. 56 , no. 9 , pp. 2440-2443 . https://doi.org/10.1063/1.334297
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