Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
We present simulations of deuterium thermal desorption spectra (TDS) from a single nm-sized spherical cavity in tungsten. We study both D2gas-filled cavities and cavities with trapping only at surface sites. The simulations are based on the diffusion theory and the kinetic model of deuterium interaction with metal surfaces. We show that the previously used approaches based on local thermodynamic equilibrium between D2gas and the subsurface solute deuterium are inadequate for simulating TDS spectra. We demonstrate the influence of cavity radius, D2gas pressure, the parameters of the surface and the bulk. The deuterium release rate from a gas-filled cavity at a fixed temperature (below the TDS peak) stays constant until the D2gas is depleted, in contrast to exponential decay observed for conventional deuterium trapping sites. Using the simulations and a simplified analytic model we demonstrate that for cavities the dependence of the TDS peak position on the heating rate does not follow exactly the Kissinger equation.
We present simulations of deuterium thermal desorption spectra (TDS) from a single nm-sized spherical cavity in tungsten. We study both D2gas-filled cavities and cavities with trapping only at surface sites. The simulations are based on the diffusion theory and the kinetic model of deuterium interaction with metal surfaces. We show that the previously used approaches based on local thermodynamic equilibrium between D2gas and the subsurface solute deuterium are inadequate for simulating TDS spectra. We demonstrate the influence of cavity radius, D2gas pressure, the parameters of the surface and the bulk. The deuterium release rate from a gas-filled cavity at a fixed temperature (below the TDS peak) stays constant until the D2gas is depleted, in contrast to exponential decay observed for conventional deuterium trapping sites. Using the simulations and a simplified analytic model we demonstrate that for cavities the dependence of the TDS peak position on the heating rate does not follow exactly the Kissinger equation.
Reaction–diffusion simulations of hydrogen isotope trapping and release from cavities in tungsten, I: Single cavity
2022
Aufsatz (Zeitschrift)
Elektronische Ressource
Unbekannt
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