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A study of butyl acetate synthesis. 4-reaction kinetics
This work was aimed at studying liquid-phase acetic acid and butyl alcohol esterification reaction (P atm =0.76 Bar),using an ion exchange resin (Lewatit K-2431) as catalyst. The effect of the absence of internal and external mass transport on catalyst particles was established in the research conditions used here. A set of assays to determine the effect of catalyst load (0.5%, 1%, 2% w/w) temperature (73°C, 80°C, 87°C) and molar ratio (1:2, 1:1, 2:1 acid/alcohol) on reaction rate was carried out and both LHHW and pseudo-homogeneous kinetic expressions were obtained, these being in good agreement with the experimental data.
A study of butyl acetate synthesis. 4-reaction kinetics
This work was aimed at studying liquid-phase acetic acid and butyl alcohol esterification reaction (P atm =0.76 Bar),using an ion exchange resin (Lewatit K-2431) as catalyst. The effect of the absence of internal and external mass transport on catalyst particles was established in the research conditions used here. A set of assays to determine the effect of catalyst load (0.5%, 1%, 2% w/w) temperature (73°C, 80°C, 87°C) and molar ratio (1:2, 1:1, 2:1 acid/alcohol) on reaction rate was carried out and both LHHW and pseudo-homogeneous kinetic expressions were obtained, these being in good agreement with the experimental data.
A study of butyl acetate synthesis. 4-reaction kinetics
Álvaro Orjuela Londoño (Autor:in) / Fernando Leiva Lenis (Autor:in) / Luis Alejandro Boyacá Mendivelso (Autor:in) / Gerardo Rodríguez Niño (Autor:in) / Luis María Carballo Suárez (Autor:in)
2006
Aufsatz (Zeitschrift)
Elektronische Ressource
Unbekannt
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