Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Spectrophotometric Detection of Glyphosate in Water by Complex Formation between Bis 5-Phenyldipyrrinate of Nickel (II) and Glyphosate
A spectrophotometric method for the determination of glyphosate based on the monitoring of a complex formation between bis 5-phenyldipyrrinate of nickel (II) and the herbicide was developed. The method showed a short response time (10 s), high selectivity (very low interference from other pesticides and salts), and high sensitivity (LOD 2.07 × 10−7 mol/L, LOQ 9.87 × 10−7 mol/L, and a Kd from 1.75 × 10−6 to 6.95 × 10−6 mol/L). The Job plot showed that complex formation occurs with a 1:1 stoichiometry. The method was successfully applied in potable, urban, groundwater, and residual-treated water samples, showing high precision (0.34–2.9%) and accuracy (87.20–119.04%). The structure of the complex was elucidated through theoretical studies demonstrating that the nickel in the bis 5-phenyldipyrrinate forms a distorted octahedral molecular geometry by expanding its coordination number through one bond with the nitrogen and another with the oxygen of the glyphosate’ carboxyl group, at distances between 1.89–2.08 Å.
Spectrophotometric Detection of Glyphosate in Water by Complex Formation between Bis 5-Phenyldipyrrinate of Nickel (II) and Glyphosate
A spectrophotometric method for the determination of glyphosate based on the monitoring of a complex formation between bis 5-phenyldipyrrinate of nickel (II) and the herbicide was developed. The method showed a short response time (10 s), high selectivity (very low interference from other pesticides and salts), and high sensitivity (LOD 2.07 × 10−7 mol/L, LOQ 9.87 × 10−7 mol/L, and a Kd from 1.75 × 10−6 to 6.95 × 10−6 mol/L). The Job plot showed that complex formation occurs with a 1:1 stoichiometry. The method was successfully applied in potable, urban, groundwater, and residual-treated water samples, showing high precision (0.34–2.9%) and accuracy (87.20–119.04%). The structure of the complex was elucidated through theoretical studies demonstrating that the nickel in the bis 5-phenyldipyrrinate forms a distorted octahedral molecular geometry by expanding its coordination number through one bond with the nitrogen and another with the oxygen of the glyphosate’ carboxyl group, at distances between 1.89–2.08 Å.
Spectrophotometric Detection of Glyphosate in Water by Complex Formation between Bis 5-Phenyldipyrrinate of Nickel (II) and Glyphosate
Aline Romero-Natale (Autor:in) / Ilaria Palchetti (Autor:in) / Mayra Avelar (Autor:in) / Enrique González-Vergara (Autor:in) / José Luis Garate-Morales (Autor:in) / Eduardo Torres (Autor:in)
2019
Aufsatz (Zeitschrift)
Elektronische Ressource
Unbekannt
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