Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Mechanisms dominating thixotropy in limestone calcined clay cement (LC3)
Abstract Limestone calcined clay cement (LC3) is a green binder with great practical importance for the cement industry. Growing application has increased the need to understand the mechanisms governing its thixotropy for better control of workability. While formation of C-S-H bridges is understood to dominate the thixotropy of ordinary Portland cement, LC3 paste displayed unique thixotropy properties. In this study, focused beam reflectance measurement, zeta potential, 1H nuclear magnetic resonance relaxometry and micro X-ray computed tomography were used to track the colloidal interaction and hydration extent within LC3 paste. Results showed that flocculation due to the negative surface charge and water affinity of calcined clay appears to be the dominating factor. This leads to a reduction of water available to contribute to fluidity of the paste and, in turn, governing the development of thixotropy over time. In addition, the dilution effect due to high clinker substitution diminishes thixotropy growth with time.
Mechanisms dominating thixotropy in limestone calcined clay cement (LC3)
Abstract Limestone calcined clay cement (LC3) is a green binder with great practical importance for the cement industry. Growing application has increased the need to understand the mechanisms governing its thixotropy for better control of workability. While formation of C-S-H bridges is understood to dominate the thixotropy of ordinary Portland cement, LC3 paste displayed unique thixotropy properties. In this study, focused beam reflectance measurement, zeta potential, 1H nuclear magnetic resonance relaxometry and micro X-ray computed tomography were used to track the colloidal interaction and hydration extent within LC3 paste. Results showed that flocculation due to the negative surface charge and water affinity of calcined clay appears to be the dominating factor. This leads to a reduction of water available to contribute to fluidity of the paste and, in turn, governing the development of thixotropy over time. In addition, the dilution effect due to high clinker substitution diminishes thixotropy growth with time.
Mechanisms dominating thixotropy in limestone calcined clay cement (LC3)
Hou, Pengkun (Autor:in) / Muzenda, Tafadzwa Ronald (Autor:in) / Li, Qinfei (Autor:in) / Chen, Heng (Autor:in) / Kawashima, Shiho (Autor:in) / Sui, Tongbo (Autor:in) / Yong, Haiyan (Autor:in) / Xie, Ning (Autor:in) / Cheng, Xin (Autor:in)
17.11.2020
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
Limestone calcined clay cement (LC3) building composition
| Europäisches Patentamt | 2023
Limestone calcined clay cement (LC3) construction composition
| Europäisches Patentamt | 2023