Chemical and rheological investigation of high-cured crumb rubber-modified asphalt: Fid-Bau Portal

Chemical and rheological investigation of high-cured crumb rubber-modified asphalt

Tang, Naipeng / Huang, Weidong / Xiao, Feipeng

Highlights • Active Polymer Index was defined to characterize the curing process of CRM Asphalt. • Interaction temperature contributed more to the degradation than interaction time. • There was linear relationship between chemical and rheological properties. • API derived from ATR-FTIR test is a good indicator of degradation of crumb rubber.

Abstract In the production of Terminal Blend (TB) rubberized asphalt, degradation of crumb rubber in asphalt matrix can help improve the storage stability and workability of crumb rubber modified asphalt. However, degradation process of crumb rubber modified (CRM) binders was not clear from molecular components to rheological properties. This study investigated chemical and rheological perspectives of the degradation process of CRM asphalt under high interaction temperature (220–280°C) and extended curing time (2–8h), namely high-cured CRM asphalt. Attenuated Total Reflection (ATR) Fourier Transform Infrared (FT-IR) Spectroscopy was used to characterize the degradation behaviors of CRM binders at varying curing temperatures and times. Active Polymer Index (API) was defined as the ratio between band areas at 978–918cm⁻¹ and 850–785cm⁻¹ of FTIR tests to characterize the released active polymer from vulcanized crumb rubber. Besides, dynamic shear rheometer (DSR) was used to perform elastic recovery (ER) test, dynamic oscillatory test and multiple stress creep recovery (MSCR) test. Test results indicated that the critical degradation temperature was 260°C in this limited study. Interaction temperature contributed more to the degradation than interaction time. Pearson correlation analysis indicated that API derived from ATR-FTIR test was a good indicator of degradation of CRM binders.