Mitigation of bidirectional solute flux in forward osmosis via membrane surface coating of zwitterion functionalized carbon nanotubes: Fid-Bau Portal

Mitigation of bidirectional solute flux in forward osmosis via membrane surface coating of zwitterion functionalized carbon nanotubes

Zou, Shiqiang / Smith, Ethan D. / Lin, Shihong / Martin, Stephen M. / He, Zhen

Abstract

Abstract Forward osmosis (FO) has emerged as a promising membrane technology to yield high-quality reusable water from various water sources. A key challenge to be solved is the bidirectional solute flux (BSF), including reverse solute flux (RSF) and forward solute flux (FSF). Herein, zwitterion functionalized carbon nanotubes (Z-CNTs) have been coated onto a commercial thin film composite (TFC) membrane, resulting in BSF mitigation via both electrostatic repulsion forces induced by zwitterionic functional groups and steric interactions with CNTs. At a coating density of 0.97 g m⁻², a significantly reduced specific RSF was observed for multiple draw solutes, including NaCl (55.5% reduction), NH4H2PO4 (83.8%), (NH4)2HPO4 (74.5%), NH4Cl (70.8%), and NH4HCO3 (61.9%). When a synthetic wastewater was applied as the feed to investigate membrane rejection, FSF was notably reduced by using the coated membrane with fewer pollutants leaked to the draw solution, including NH4 ⁺-N (46.3% reduction), NO2 ⁻-N (37.0%), NO3 ⁻-N (30.3%), K⁺ (56.1%), PO4 ³⁻-P (100%), and Mg²⁺ (100%). When fed with real wastewater, a consistent water flux was achieved during semi-continuous operation with enhanced fouling resistance. This study is among the earliest efforts to address BSF control via membrane modification, and the results will encourage further exploration of effective strategies to reduce BSF.

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Highlights • Coating Z-CNT on FO active layer did not adversely impact water transport. • BSF mitigation was achieved via zwitterionic groups and electrostatic repulsion. • Up to 83.8% reduction of reverse solute flux was observed with Z-CNT coating. • Up to 100% reduction of forward solute flux was achieved with Z-CNT coating. • Consistent water flux was obtained in a 12-day operation with reversible fouling.