Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Rate constant for the reaction of ozone with diethyl sulfide
AbstractThe rate constant for the reaction of diethyl sulfide (DES; C2H5SC2H5) with ozone was determined for the first time, which was (2.77±0.27)×10−19cm3molecule−1s−1 under a room temperature of (289±1)K. Experiments were conducted under supposedly pseudo-first-order decay conditions, keeping [DES]0>50[O3]0, but having different combinations of [DES]0 and [O3]0. Cyclohexane was added into the reactor to eliminate the effect of OH radicals. The wall decay of ozone and the role of cyclohexane were also discussed in the present work.
Rate constant for the reaction of ozone with diethyl sulfide
AbstractThe rate constant for the reaction of diethyl sulfide (DES; C2H5SC2H5) with ozone was determined for the first time, which was (2.77±0.27)×10−19cm3molecule−1s−1 under a room temperature of (289±1)K. Experiments were conducted under supposedly pseudo-first-order decay conditions, keeping [DES]0>50[O3]0, but having different combinations of [DES]0 and [O3]0. Cyclohexane was added into the reactor to eliminate the effect of OH radicals. The wall decay of ozone and the role of cyclohexane were also discussed in the present work.
Rate constant for the reaction of ozone with diethyl sulfide
Du, Lin (Autor:in) / Xu, Yongfu (Autor:in) / Ge, Maofa (Autor:in) / Jia, Long (Autor:in)
Atmospheric Environment ; 41 ; 7434-7439
24.05.2007
6 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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