Implications of different aerosol species to direct radiative forcing and atmospheric heating rate: Fid-Bau Portal

Implications of different aerosol species to direct radiative forcing and atmospheric heating rate

Srivastava, A.K. / Mehrotra, Bharat Ji / Singh, Abhishek / Singh, V. / Bisht, D.S. / Tiwari, S. / Srivastava, Manoj K.

Abstract The optical and radiative characteristics of water-soluble and carbonaceous aerosol species in the PM2.5 samples were examined for a representative megacity over the Indo-Gangetic Basin (IGB). Aerosol optical and radiative transfer models were used to extract sulphate (SO4), nitrate (NO3), organic carbon (OC) and elemental carbon (EC) from the observations done in 2012. Initial results suggest that the mass concentration of OC dominated over other species, but impacts on optical characteristics were mostly due to the SO4 aerosols. Further, EC shows relatively large impact on radiative forcing. The aerosol optical depth (AOD) at 500 nm for SO4, NO3, EC and OC was found to be contributing ~36%, 20%, 27% and 9%, respectively in the total AOD value (0.61 ± 0.18) during the entire study period. The single scattering albedo (SSA) for SO4 and NO3 was high and suggested their scattering nature; however, being the highly absorbing species, EC was found to show the lowest values of SSA during the study period. SSA for OC was, however, ~0.70, which was found to show the second highest warming species in the atmosphere with contribution of ~10%, after EC, which caused the highest warming (~70%), to the total atmospheric forcing.

Highlights • Optical and radiative characteristics of aerosol species of PM2.5 samples were examined. • The SO4 contributed highest (~36%) to the total AOD and lowest (~9%) for OC. • EC contributed highest to the total ADRFATM, though has lowest contribution to the PM2.5. • OC is the second highest contributor (~10%) as warming species to the total ADRFATM.