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Catalytic wet peroxide oxidation of phenol over Al–Cu or Al–Fe modified clays

Carriazo, J.G. / Guelou, E. / Barrault, J. / Tatibouët, J.M. / Moreno, S.

AbstractAl–Fe or Al–Cu modified clays were prepared from two natural montmorillonites and employed in the phenol oxidation with hydrogen peroxide in water. The samples were efficient in phenol elimination under mild experimental conditions (atmospheric pressure, 293 K and small quantities of hydrogen peroxide) without considerable leaching of the metal ions. The clays modified with Fe achieved high conversions of phenol and TOC thus showing to be very selective towards the formation of CO2 and H2O.

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Catalytic wet peroxide oxidation of phenol over Al–Cu or Al–Fe modified clays

Carriazo, J.G. / Guelou, E. / Barrault, J. / Tatibouët, J.M. / Moreno, S.

AbstractAl–Fe or Al–Cu modified clays were prepared from two natural montmorillonites and employed in the phenol oxidation with hydrogen peroxide in water. The samples were efficient in phenol elimination under mild experimental conditions (atmospheric pressure, 293 K and small quantities of hydrogen peroxide) without considerable leaching of the metal ions. The clays modified with Fe achieved high conversions of phenol and TOC thus showing to be very selective towards the formation of CO2 and H2O.

Catalytic wet peroxide oxidation of phenol over Al–Cu or Al–Fe modified clays

Carriazo, J.G. / Guelou, E. / Barrault, J. / Tatibouët, J.M. / Moreno, S.

AbstractAl–Fe or Al–Cu modified clays were prepared from two natural montmorillonites and employed in the phenol oxidation with hydrogen peroxide in water. The samples were efficient in phenol elimination under mild experimental conditions (atmospheric pressure, 293 K and small quantities of hydrogen peroxide) without considerable leaching of the metal ions. The clays modified with Fe achieved high conversions of phenol and TOC thus showing to be very selective towards the formation of CO2 and H2O.

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Titel:

Catalytic wet peroxide oxidation of phenol over Al–Cu or Al–Fe modified clays

Beteiligte:

Carriazo, J.G. (Autor:in) / Guelou, E. (Autor:in) / Barrault, J. (Autor:in) / Tatibouët, J.M. (Autor:in) / Moreno, S. (Autor:in)

Erschienen in:

Applied Clay Science ; 22 ; 303-308

Erscheinungsdatum:

16.04.2003

Format / Umfang:

6 pages

ISSN:

DOI:

https://doi.org/10.1016/S0169-1317(03)00124-8

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

Pillared clays , Fe-modified clays , Phenol oxidation , CWPO reaction , Wastewater

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