Surface tensions of solutions containing dicarboxylic acid mixtures: Fid-Bau Portal

Surface tensions of solutions containing dicarboxylic acid mixtures

Lee, Jae Young / Hildemann, Lynn M.

Abstract Organic solutes tend to lower the surface tension of cloud condensation nuclei, allowing them to more readily activate. The surface tension of various dicarboxylic acid aerosol mixtures was measured at 20 °C using the Wilhelmy plate method. At lower concentrations, the surface tension of a solution with equi-molar mixtures of dicarboxylic acids closely followed that of a solution with the most surface-active organic component alone. Measurements of surface tension for these mixtures were lower than predictions using Henning's model and the modified Szyszkowski equation, by ∼1–2%. The calculated maximum surface excess (Γmax) and inverse Langmuir adsorption coefficient (β) from the modified Szyszkowski equation were both larger than measured values for 6 of the 7 mixtures tested. Accounting for the reduction in surface tension in the Köhler equation reduced the critical saturation ratio for these multi-component mixtures – changes were negligible for dry diameters of 0.1 and 0.5 μm, but a reduction from 1.0068 to 1.0063 was seen for the 4-dicarboxylic acid mixture with a dry diameter of 0.05 μm.

Highlights • Surface tension of dicarboxylic acid mixture was measured using Wilhelmy plate method. • Surface tension of dicarboxylic acid mixture follows the most surface-active one. • Modified Szyszkowski equation systematically overestimates the surface tensions. • Henning's model systematically overestimates the surface tensions. • The critical supersaturation ratio is reduced by adding dicarboxylic acids.