Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Atmospheric chemistry of CF3CCH: Kinetics, products, mechanism of gas-phase reaction with OH radicals, and atmospheric implications-an effort for novel ‘class’ of refrigerant
Abstract We use the relative method to first evaluate the atmospheric chemistry of CF3CCH that would play significant role in novel refrigerant development. We show that rate constant (k OH) for the gas-phase reaction of CF3CCH with OH radicals at 298 K is measured to be (2.15 ± 0.02) × 10−13 cm3 molecule−1 s−1, with Arrhenius expression as k OH=(3.40 ± 0.46) × 10−12 exp ((-832.70 ± 38.86)/T). Subject to the short atmospheric lifetime of CF3CCH of 53.9 d and radiative efficiency of 0.071 W m−2 ppb−1, the global warming potentials (GWPs) for 20, 100, and 500 yr are 42, 11, and 3, respectively. CF3CCH emissions are predicated to produce CO, CO2, COF2 and CF3O3CF3 as the main carbon-containing products. The photochemical ozone creation potential of the CF3CCH is 2.49 and 1.05 in Northwestern European and US urban areas, respectively. Density functional theory calculations further explained its possible degradation mechanism in atmosphere. Our work provides basic evidence for future molecular design of environmental-friendly CC containing substances.
Highlights Great environmental potential of CF3CCH as novel refrigerant was suggested. Atmospheric lifetime is ∼53.9 d, and POCP is 1.05–2.49. 100-year GWP is 11. CO, CO2, COF2 and CF3O3CF3 are main carbon-containing products. Complete degradation mechanism of CF3CCH in atmosphere was proposed. CC redistributes electrons in molecules, slightly reducing OH-initiated reactivity.
Atmospheric chemistry of CF3CCH: Kinetics, products, mechanism of gas-phase reaction with OH radicals, and atmospheric implications-an effort for novel ‘class’ of refrigerant
Abstract We use the relative method to first evaluate the atmospheric chemistry of CF3CCH that would play significant role in novel refrigerant development. We show that rate constant (k OH) for the gas-phase reaction of CF3CCH with OH radicals at 298 K is measured to be (2.15 ± 0.02) × 10−13 cm3 molecule−1 s−1, with Arrhenius expression as k OH=(3.40 ± 0.46) × 10−12 exp ((-832.70 ± 38.86)/T). Subject to the short atmospheric lifetime of CF3CCH of 53.9 d and radiative efficiency of 0.071 W m−2 ppb−1, the global warming potentials (GWPs) for 20, 100, and 500 yr are 42, 11, and 3, respectively. CF3CCH emissions are predicated to produce CO, CO2, COF2 and CF3O3CF3 as the main carbon-containing products. The photochemical ozone creation potential of the CF3CCH is 2.49 and 1.05 in Northwestern European and US urban areas, respectively. Density functional theory calculations further explained its possible degradation mechanism in atmosphere. Our work provides basic evidence for future molecular design of environmental-friendly CC containing substances.
Highlights Great environmental potential of CF3CCH as novel refrigerant was suggested. Atmospheric lifetime is ∼53.9 d, and POCP is 1.05–2.49. 100-year GWP is 11. CO, CO2, COF2 and CF3O3CF3 are main carbon-containing products. Complete degradation mechanism of CF3CCH in atmosphere was proposed. CC redistributes electrons in molecules, slightly reducing OH-initiated reactivity.
Atmospheric chemistry of CF3CCH: Kinetics, products, mechanism of gas-phase reaction with OH radicals, and atmospheric implications-an effort for novel ‘class’ of refrigerant
Zhang, Tongyun (Autor:in) / Zhang, Chengping (Autor:in) / Ma, Xiaoxun (Autor:in) / Quan, Hengdao (Autor:in)
Atmospheric Environment ; 294
05.11.2022
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
Atmospheric oxidation mechanism of acenaphthene initiated by OH radicals
| Elsevier | 2020