Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Influence of aluminates on the hydration kinetics of tricalcium silicate
AbstractWe used a combination of experimental and modelling techniques to study the effect of NaAlO2 on C3S hydration. pH sensitive inhibition of C3S hydration occurred at an early age of reaction, but was followed by an increased amount of hydrates formed later. Most results suggest that aluminates hinder C3S dissolution. It is hypothesised that this takes place in active dissolution areas, present with a higher density on finer particles. Annealing reduces their number and increases retardation for a given dosage of aluminates. The view that aluminates act by hindering dissolution is supported by molecular dynamics (MD) simulations. They establish that aluminates can adsorb on the hydroxylated C3S mainly through strong ionic interactions between aluminate and calcium ions on the surface of silicate. Upon progress of hydration and at higher pH values, the binding strength of aluminates to the hydroxylated C3S decreases so that its passivating effect, and retardation, are reduced.
Influence of aluminates on the hydration kinetics of tricalcium silicate
AbstractWe used a combination of experimental and modelling techniques to study the effect of NaAlO2 on C3S hydration. pH sensitive inhibition of C3S hydration occurred at an early age of reaction, but was followed by an increased amount of hydrates formed later. Most results suggest that aluminates hinder C3S dissolution. It is hypothesised that this takes place in active dissolution areas, present with a higher density on finer particles. Annealing reduces their number and increases retardation for a given dosage of aluminates. The view that aluminates act by hindering dissolution is supported by molecular dynamics (MD) simulations. They establish that aluminates can adsorb on the hydroxylated C3S mainly through strong ionic interactions between aluminate and calcium ions on the surface of silicate. Upon progress of hydration and at higher pH values, the binding strength of aluminates to the hydroxylated C3S decreases so that its passivating effect, and retardation, are reduced.
Influence of aluminates on the hydration kinetics of tricalcium silicate
Pustovgar, Elizaveta (Autor:in) / Mishra, Ratan K. (Autor:in) / Palacios, Marta (Autor:in) / d'Espinose de Lacaillerie, Jean-Baptiste (Autor:in) / Matschei, Thomas (Autor:in) / Andreev, Andrey S. (Autor:in) / Heinz, Hendrik (Autor:in) / Verel, Rene (Autor:in) / Flatt, Robert J. (Autor:in)
Cement and Concrete Research ; 100 ; 245-262
29.06.2017
18 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
Influence of aluminates on the hydration kinetics of tricalcium silicate
| British Library Online Contents | 2017
Influence of aluminates on the hydration kinetics of tricalcium silicate
| British Library Online Contents | 2017
Influence of aluminates on the hydration kinetics of tricalcium silicate
| Online Contents | 2017
Influence of aluminates on the hydration kinetics of tricalcium silicate
| British Library Online Contents | 2017
The hydration of tricalcium silicate
| Springer Verlag | 1984