Sources and transport of black carbon at the California

Sources and transport of black carbon at the California–Mexico border

Shores, Christopher A. / Klapmeyer, Michael E. / Quadros, Marina E. / Marr, Linsey C.

Abstract At international border areas that suffer from poor air quality, assessment of pollutant sources and transport across the border is important for designing effective air quality management strategies. As part of the Cal-Mex 2010 field campaign at the US–Mexico border in San Diego and Tijuana, we measured black carbon (BC) concentrations at three locations in Mexico and one in the United States. The measurements were intended to support the following objectives: to characterize the spatial and temporal variability in BC, to estimate the BC emission inventory, to identify potential source areas of BC emissions, and to assess the cross-border transport of BC. Concentrations at Parque Morelos, the campaign's supersite, averaged 2.2 μg m⁻³ and reached a maximum value of 55.9 μg m⁻³ (1-min average). Sharp, regularly occurring peaks around midnight were suggestive of clandestine industrial activity. BC concentrations were more than two times higher, on average, in Tijuana compared to San Diego. BC and carbon monoxide (CO) were strongly correlated at the three sites in Mexico. The ΔBC/ΔCO ratio of 5.6 ± 0.5 μg m⁻³ ppm⁻¹ in Tijuana, or 4.7 ± 0.5 μg m⁻³ ppm⁻¹ when adjusted for seasonal temperature effects to represent an annual average, was comparable to that in other urban areas. Tijuana's emissions of BC were estimated to be 230–890 metric tons per year, 6–23% of those estimated for San Diego. Large uncertainties in this estimate stem mainly from uncertainties in the CO emission inventory, and the lower end of the estimate is more likely to be accurate. Patterns in concentrations and winds suggest that BC in Tijuana was usually of local origin. Under typical summertime conditions such as those observed during the study, transport from Tijuana into the US was common, crossing the border in a northeasterly direction, sometimes as far east as Imperial County at the eastern edge of California.

Graphical abstract Display Omitted Highlights ► We measured black carbon at four locations in San Diego and Tijuana. ► Black carbon was at least two times higher in Tijuana than in San Diego. ► We estimated Tijuana's black carbon emissions to be 230–890 metric tons per year. ► Emissions of black carbon were sometimes transported from Tijuana into the US.