Physiochemical properties of carbonaceous aerosol from agricultural residue burning: Density, volatility, and hygroscopicity: Fid-Bau Portal

Physiochemical properties of carbonaceous aerosol from agricultural residue burning: Density, volatility, and hygroscopicity

Li, Chunlin / Hu, Yunjie / Chen, Jianmin / Ma, Zhen / Ye, Xingnan / Yang, Xin / Wang, Lin / Wang, Xinming / Mellouki, Abdelwahid

Abstract

Abstract Size-resolved effective density, mixing state, and hygroscopicity of smoke particles from five kinds of agricultural residues burning were characterized using an aerosol chamber system, including a volatility/hygroscopic tandem differential mobility analyzer (V/H-TDMA) combined with an aerosol particle mass analyzer (APM). To profile relationship between the thermodynamic properties and chemical compositions, smoke PM1.0 and PM2.5 were also measured for the water soluble inorganics, mineral elements, and carbonaceous materials like organic carbon (OC) and elemental carbon (EC). Smoke particle has a density of 1.1–1.4 g cm⁻³, and hygroscopicity parameter (κ) derived from hygroscopic growth factor (GF) of the particles ranges from 0.20 to 0.35. Size- and fuel type-dependence of density and κ are obvious. The integrated effective densities (ρ) and hygroscopicity parameters (κ) both scale with alkali species, which could be parameterized as a function of organic and inorganic mass fraction (f org &f inorg) in smoke PM1.0 and PM2.5: $ρ^{- 1} = f_{i n o r g} \cdot ρ_{i n o r g}^{- 1} + f_{o r g} \cdot ρ_{o r g}^{- 1}$ and $κ = f_{i n o r g} \cdot κ_{i n o r g} + f_{o r g} \cdot κ_{o r g}$ . The extrapolated values of ρinorg and ρorg are 2.13 and 1.14 g cm⁻³ in smoke PM1.0, while the characteristic κ values of organic and inorganic components are about 0.087 and 0.734, which are similar to the bulk density and κ calculated from predefined chemical species and also consistent with those values observed in ambient air. Volatility of smoke particle was quantified as volume fraction remaining (VFR) and mass fraction remaining (MFR). The gradient temperature of V-TDMA was set to be consistent with the splitting temperature in the OC-EC measurement (OC1 and OC2 separated at 150 and 250 °C). Combing the thermogram data and chemical composition of smoke PM1.0, the densities of organic matter (OM1 and OM2 correspond to OC1 and OC2) are estimated as 0.61–0.90 and 0.86–1.13 g cm⁻³, and the ratios of OM1/OC1 and OM2/OC2 are 1.07 and 1.29 on average, indicating more volatile organic materials have less density and lower OM/OC ratios in the external mixed smoke particles.

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Highlights • Effective densities, volatility, and hygroscopicity of smoke particle were measured using V/H-TDMA-APM system. • Smoke particles were produced from filed burning simulation of crop straws with aerosol chamber system. • Density, volatility, and hygroscopicity of smoke particles were measured using V/H-TDMA-APM system. • Integrated density and hygroscopicity of smoke particles scale with the inorganic mass fraction. • More volatile organic materials have less density and lower OM/OC ratios in the external mixed smoke particles.