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Properties of polymethyl methacrylate-based nanocomposites: Reinforced with ultra-long chitin nanofiber extracted from crab shells
Highlights Using waste crab shells to develop high-performance composites by simple method. Combining the anatomic analysis of crab shell with the design of composite. Introducing a 4-step all-mechanical treatment to prepare ultra-long chitin fiber. Incorporation of chitin nanofiber improves properties of PMMA/Chitin composite.
Abstract Ultra-long chitin nanofibers were incorporated into polymethyl methacrylate (PMMA) resin to prepared PMMA/Chitin nanocomposites with improved properties. Transmission electron microscopy (TEM) images showed that through the introduced 4-step all-mechanical treatment, the average aspect ratio of the obtained chitin fiber was up to 1000 with the length at dozens of micron range. Due to the laminated structure formed by “layer-by-layer” effect, tensile strength and Young’s modulus of the prepared composite were significantly enhanced after the filling of chitin nanofibers, as compared with neat PMMA. Light transmittance test indicated that increasing the fiber content causes little light scattering because the nano-scalar network which is smaller enough than the visible wavelength could well preserve the original transparency of PMMA. Furthermore, chitin nanofiber film with extremely low thermal expansion improved the thermal stability of PMMA in a great degree. This could lead to various commercial applications including flexible electronic printing, organic thin-film photovoltaic devices, and is a significantly environmental move towards the sustainable utilization of marine-river crab shell wastes.
Properties of polymethyl methacrylate-based nanocomposites: Reinforced with ultra-long chitin nanofiber extracted from crab shells
Highlights Using waste crab shells to develop high-performance composites by simple method. Combining the anatomic analysis of crab shell with the design of composite. Introducing a 4-step all-mechanical treatment to prepare ultra-long chitin fiber. Incorporation of chitin nanofiber improves properties of PMMA/Chitin composite.
Abstract Ultra-long chitin nanofibers were incorporated into polymethyl methacrylate (PMMA) resin to prepared PMMA/Chitin nanocomposites with improved properties. Transmission electron microscopy (TEM) images showed that through the introduced 4-step all-mechanical treatment, the average aspect ratio of the obtained chitin fiber was up to 1000 with the length at dozens of micron range. Due to the laminated structure formed by “layer-by-layer” effect, tensile strength and Young’s modulus of the prepared composite were significantly enhanced after the filling of chitin nanofibers, as compared with neat PMMA. Light transmittance test indicated that increasing the fiber content causes little light scattering because the nano-scalar network which is smaller enough than the visible wavelength could well preserve the original transparency of PMMA. Furthermore, chitin nanofiber film with extremely low thermal expansion improved the thermal stability of PMMA in a great degree. This could lead to various commercial applications including flexible electronic printing, organic thin-film photovoltaic devices, and is a significantly environmental move towards the sustainable utilization of marine-river crab shell wastes.
Properties of polymethyl methacrylate-based nanocomposites: Reinforced with ultra-long chitin nanofiber extracted from crab shells
Chen, Chuchu (Autor:in) / Li, Dagang (Autor:in) / Hu, Qinqin (Autor:in) / Wang, Ru (Autor:in)
22.11.2013
8 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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