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Polycarboxylate superplasticizer for machine-made sand concrete prestressed component and preparation method of polycarboxylate superplasticizer
The invention discloses a polycarboxylate superplasticizer for a machine-made sand concrete prestressed component and a preparation method of the polycarboxylate superplasticizer. The polycarboxylatesuperplasticizer is prepared from the following raw materials in parts by mass: 50-100 parts of polyether macromonomer, 20-40 parts of an ester macromonomer, 5-15 parts of maleic acid-beta-cyclodextrin, 5-15 parts of styrene, 30-60 parts of an acrylic monomer, 10-30 parts of unsaturated phosphate and 5-25 parts of an ammonium cation unsaturated monomer in a free radical polymerization manner so asto prepare a polymer with the molecular weight of 15000-80000; and 0-4 parts of an organic silicon defoamer, 0-10 parts of an early strength agent and 5-15 parts of a sacrificial agent are compounded, and then an alkaline solution is added for neutralization. The polycarboxylate superplasticizer has high tolerance to the stone powder content of machine-made sand concrete, good water reducing andviscosity reducing effects and an early strength function, meets the production requirements of machine-made sand concrete prestressed components in the fields of railways, highways, water conservancyand the like, and in particular, is used for preparing high-strength prestressed components with low water-binder ratios.
一种机制砂混凝土预应力构件用聚羧酸减水剂及其制备方法,该聚羧酸减水剂通过下列质量份数的原材料制备而成:聚醚大单体50~100份、酯类大单体20~40份、马来酸‑β‑环糊精5~15份、苯乙烯5~15份、丙烯酸类单体30~60份、不饱和磷酸酯10~30份、铵阳离子不饱和单体5~25份以自由基聚合的方式制备出分子量为15000‑80000的聚合物,复配有机硅类消泡剂0~4份、早强剂0~10份、牺牲剂5~15份,然后加入碱溶液中和。本发明提供的聚羧酸减水剂对机制砂混凝土石粉含量容忍度高,减水降粘效果好,并具有早强功能,满足铁路、公路、水利等领域的机制砂混凝土预应力构件的生产需求,特别是低水胶比的高强度预应力构件的制备。
Polycarboxylate superplasticizer for machine-made sand concrete prestressed component and preparation method of polycarboxylate superplasticizer
The invention discloses a polycarboxylate superplasticizer for a machine-made sand concrete prestressed component and a preparation method of the polycarboxylate superplasticizer. The polycarboxylatesuperplasticizer is prepared from the following raw materials in parts by mass: 50-100 parts of polyether macromonomer, 20-40 parts of an ester macromonomer, 5-15 parts of maleic acid-beta-cyclodextrin, 5-15 parts of styrene, 30-60 parts of an acrylic monomer, 10-30 parts of unsaturated phosphate and 5-25 parts of an ammonium cation unsaturated monomer in a free radical polymerization manner so asto prepare a polymer with the molecular weight of 15000-80000; and 0-4 parts of an organic silicon defoamer, 0-10 parts of an early strength agent and 5-15 parts of a sacrificial agent are compounded, and then an alkaline solution is added for neutralization. The polycarboxylate superplasticizer has high tolerance to the stone powder content of machine-made sand concrete, good water reducing andviscosity reducing effects and an early strength function, meets the production requirements of machine-made sand concrete prestressed components in the fields of railways, highways, water conservancyand the like, and in particular, is used for preparing high-strength prestressed components with low water-binder ratios.
一种机制砂混凝土预应力构件用聚羧酸减水剂及其制备方法,该聚羧酸减水剂通过下列质量份数的原材料制备而成:聚醚大单体50~100份、酯类大单体20~40份、马来酸‑β‑环糊精5~15份、苯乙烯5~15份、丙烯酸类单体30~60份、不饱和磷酸酯10~30份、铵阳离子不饱和单体5~25份以自由基聚合的方式制备出分子量为15000‑80000的聚合物,复配有机硅类消泡剂0~4份、早强剂0~10份、牺牲剂5~15份,然后加入碱溶液中和。本发明提供的聚羧酸减水剂对机制砂混凝土石粉含量容忍度高,减水降粘效果好,并具有早强功能,满足铁路、公路、水利等领域的机制砂混凝土预应力构件的生产需求,特别是低水胶比的高强度预应力构件的制备。
Polycarboxylate superplasticizer for machine-made sand concrete prestressed component and preparation method of polycarboxylate superplasticizer
一种机制砂混凝土预应力构件用聚羧酸减水剂及其制备方法
JIN HAO (Autor:in) / LI HUAJIAN (Autor:in) / YI ZHONGLAI (Autor:in) / HUANG FALI (Autor:in) / WANG ZHEN (Autor:in) / XIE YONGJIANG (Autor:in) / YUAN ZHENGCHENG (Autor:in) / WEN HAO (Autor:in) / ZHONG XINHUA (Autor:in) / XIE QINGQING (Autor:in)
28.08.2020
Patent
Elektronische Ressource
Chinesisch
IPC:
C04B
Kalk
,
LIME
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