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Solid electrolyte and preparation method thereof
The invention discloses a solid electrolyte and a preparation method thereof, and relates to the technical field of electrolytes. The solid electrolyte comprises the following components: powder and an adhesive, wherein the mass ratio of the powder to the adhesive is (20-50): (50-80); the powder comprises the following components in percentage by mass: 80%-98% of ZrO2 and 2%-5% of a stabilizer, and the adhesive comprises the following components in percentage by mass: 80%-95% of paraffin, 1%-7% of a first additive and 0.1%-0.8% of a second additive; the preparation method comprises the following steps: mixing 80wt%-98wt% of ZrO2 and 2wt%-5wt% of a stabilizer to obtain powder; carrying out ultrafine treatment on the obtained powder; mixing the powder subjected to the ultrafine treatment with an adhesive, and mixing a mixture obtained after mixing; and after mixing, granulating, injecting, degreasing and sintering to prepare the solid electrolyte. Therefore, the problem of poor thermal shock property of the zirconium oxide tube solid electrolyte in the prior art is solved.
本发明公开了固体电解质及其制备方法,涉及电解质技术领域。固体电解质的组成成分包括:粉体与粘接剂,粉体与粘接剂的质量比为20‑50:50‑80;粉体的质量百分比组成成分包括:80%‑98%ZrO2和2%‑5%稳定剂,粘接剂的质量百分比组成成分包括:80%‑95%石蜡、1%‑7%第一添加剂以及0.1%‑0.8%第二添加剂;将80wt%‑98wt%的ZrO2与2wt%‑5wt%的稳定剂进行混合得到粉体;将得到的粉体进行超细化处理;将进行超细化处理后的粉体与粘接剂进行混合,将混合后得到的混合物进行混炼;混炼之后再进行造粒、注射以及脱脂烧结,制得固体电解质;从而解决了现有技术中氧化锆管固体电解质的热震性不佳的问题。
Solid electrolyte and preparation method thereof
The invention discloses a solid electrolyte and a preparation method thereof, and relates to the technical field of electrolytes. The solid electrolyte comprises the following components: powder and an adhesive, wherein the mass ratio of the powder to the adhesive is (20-50): (50-80); the powder comprises the following components in percentage by mass: 80%-98% of ZrO2 and 2%-5% of a stabilizer, and the adhesive comprises the following components in percentage by mass: 80%-95% of paraffin, 1%-7% of a first additive and 0.1%-0.8% of a second additive; the preparation method comprises the following steps: mixing 80wt%-98wt% of ZrO2 and 2wt%-5wt% of a stabilizer to obtain powder; carrying out ultrafine treatment on the obtained powder; mixing the powder subjected to the ultrafine treatment with an adhesive, and mixing a mixture obtained after mixing; and after mixing, granulating, injecting, degreasing and sintering to prepare the solid electrolyte. Therefore, the problem of poor thermal shock property of the zirconium oxide tube solid electrolyte in the prior art is solved.
本发明公开了固体电解质及其制备方法,涉及电解质技术领域。固体电解质的组成成分包括:粉体与粘接剂,粉体与粘接剂的质量比为20‑50:50‑80;粉体的质量百分比组成成分包括:80%‑98%ZrO2和2%‑5%稳定剂,粘接剂的质量百分比组成成分包括:80%‑95%石蜡、1%‑7%第一添加剂以及0.1%‑0.8%第二添加剂;将80wt%‑98wt%的ZrO2与2wt%‑5wt%的稳定剂进行混合得到粉体;将得到的粉体进行超细化处理;将进行超细化处理后的粉体与粘接剂进行混合,将混合后得到的混合物进行混炼;混炼之后再进行造粒、注射以及脱脂烧结,制得固体电解质;从而解决了现有技术中氧化锆管固体电解质的热震性不佳的问题。
Solid electrolyte and preparation method thereof
固体电解质及其制备方法
HU SHUXIN (Autor:in) / LI CHUNCHAO (Autor:in) / YE JIANGHAI (Autor:in) / SHI MENGQIANG (Autor:in)
26.04.2022
Patent
Elektronische Ressource
Chinesisch
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