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ADMIXTURE COMPOSITION FOR CEMENT AND PRODUCTION METHOD THEREFOR, AND CEMENT COMPOSITION AND PRODUCTION METHOD THEREFOR
PROBLEM TO BE SOLVED: To provide an admixture composition for cement that exhibits sufficient strength under a low-temperature environment, has excellent hydration activity and shows good quick-hardening performance and at the same time can sufficiently ensure predetermined flowability, and can suppress occurrence of initial shrinkage crack due to its self-shrinkage and a production method therefor, and to provide a cement composition and a production method therefor.SOLUTION: An admixture composition for cement includes a quick-hardening additive for cement containing CA-based mineral phase, gypsum, an alkali sulfate compound, a calcium salt and lithium carbonate, contains 36 to 55 mass% of CA-based mineral, 0.3 to 1.7 mass% of an alkali sulfate compound (in terms of sodium sulfate), 0.01 to 1.3 mass% of lithium carbonate (in terms of lithium) and 1 to 14 mass% of a calcium salt (in terms of calcium hydroxide), has a mass ratio of gypsum content (in terms of anhydrous gypsum)/CA-based mineral phase content of 0.5 to 1.2 and has a crystallite diameter of CA-based mineral phase of 150 to 500 nm and a lattice constant of 11.940 to 11.975Å as measured by X-ray diffraction. The cement composition contains the quick-hardening additive for cement, gypsum, an alkali sulfate compound and a calcium salt, lithium carbonate and cement.SELECTED DRAWING: None
【課題】 低温環境下で十分な強度を発現し、水和活性が優れて良好な急硬性能を示すと同時に所定の流動性を十分に確保することができ、自己収縮による初期収縮ひび割れの発生を抑制することができる、セメント用混和組成物及びその製造方法、並びにセメント組成物及びその製造方法を提供する。【解決手段】 セメント用混和組成物は、C12A7系鉱物相を含有するセメント用急硬性添加材と、石膏と、硫酸アルカリ化合物と、カルシウム塩と炭酸リチウムとを含み、C12A7系鉱物を36〜55質量%、硫酸アルカリ化合物(硫酸ナトリウム換算)を0.3〜1.7質量%、炭酸リチウム(リチウム換算)を0.01〜1.3質量%、カルシウム塩(水酸化カルシウム換算)を1〜14質量%含有し、石膏(無水石膏換算)/C12A7系鉱物相の含有量の質量比が0.5〜1.2であり、X線回折で測定したC12A7系鉱物相の結晶子径が150〜500nmで格子定数が11.940〜11.975Åであり、セメント組成物は、前記セメント用急硬性添加材と、石膏と、硫酸アルカリ化合物と、カルシウム塩と、炭酸リチウムとセメントとを含む。【選択図】 なし
ADMIXTURE COMPOSITION FOR CEMENT AND PRODUCTION METHOD THEREFOR, AND CEMENT COMPOSITION AND PRODUCTION METHOD THEREFOR
PROBLEM TO BE SOLVED: To provide an admixture composition for cement that exhibits sufficient strength under a low-temperature environment, has excellent hydration activity and shows good quick-hardening performance and at the same time can sufficiently ensure predetermined flowability, and can suppress occurrence of initial shrinkage crack due to its self-shrinkage and a production method therefor, and to provide a cement composition and a production method therefor.SOLUTION: An admixture composition for cement includes a quick-hardening additive for cement containing CA-based mineral phase, gypsum, an alkali sulfate compound, a calcium salt and lithium carbonate, contains 36 to 55 mass% of CA-based mineral, 0.3 to 1.7 mass% of an alkali sulfate compound (in terms of sodium sulfate), 0.01 to 1.3 mass% of lithium carbonate (in terms of lithium) and 1 to 14 mass% of a calcium salt (in terms of calcium hydroxide), has a mass ratio of gypsum content (in terms of anhydrous gypsum)/CA-based mineral phase content of 0.5 to 1.2 and has a crystallite diameter of CA-based mineral phase of 150 to 500 nm and a lattice constant of 11.940 to 11.975Å as measured by X-ray diffraction. The cement composition contains the quick-hardening additive for cement, gypsum, an alkali sulfate compound and a calcium salt, lithium carbonate and cement.SELECTED DRAWING: None
【課題】 低温環境下で十分な強度を発現し、水和活性が優れて良好な急硬性能を示すと同時に所定の流動性を十分に確保することができ、自己収縮による初期収縮ひび割れの発生を抑制することができる、セメント用混和組成物及びその製造方法、並びにセメント組成物及びその製造方法を提供する。【解決手段】 セメント用混和組成物は、C12A7系鉱物相を含有するセメント用急硬性添加材と、石膏と、硫酸アルカリ化合物と、カルシウム塩と炭酸リチウムとを含み、C12A7系鉱物を36〜55質量%、硫酸アルカリ化合物(硫酸ナトリウム換算)を0.3〜1.7質量%、炭酸リチウム(リチウム換算)を0.01〜1.3質量%、カルシウム塩(水酸化カルシウム換算)を1〜14質量%含有し、石膏(無水石膏換算)/C12A7系鉱物相の含有量の質量比が0.5〜1.2であり、X線回折で測定したC12A7系鉱物相の結晶子径が150〜500nmで格子定数が11.940〜11.975Åであり、セメント組成物は、前記セメント用急硬性添加材と、石膏と、硫酸アルカリ化合物と、カルシウム塩と、炭酸リチウムとセメントとを含む。【選択図】 なし
ADMIXTURE COMPOSITION FOR CEMENT AND PRODUCTION METHOD THEREFOR, AND CEMENT COMPOSITION AND PRODUCTION METHOD THEREFOR
セメント用混和組成物及びその製造方法、並びにセメント組成物及びその製造方法
KANO KAZUHIRO (Autor:in) / KIKO TOMOKO (Autor:in) / KAMIKOUCHI TAKASHI (Autor:in) / ITO KYOKO (Autor:in) / KIKUCHI SADATO (Autor:in) / HIRANO YUKI (Autor:in) / OZAWA SATOSHI (Autor:in)
15.11.2018
Patent
Elektronische Ressource
Japanisch
IPC:
C04B
Kalk
,
LIME
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