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High-molecular polysilane and method for the production thereof for producing pre-ceramic molded bodies
A method produces a polysilane by reacting at least two silane monomers and at least one alkali metal. The silane monomers have the following structural units: at least one aryl group, at least one alkyl group, at least one alkenyl group, and at least three halogen atoms. Wherein at least three of the halogen atoms are bonded to a silicon atom of one of the silane monomers, and the reaction step takes place in an ether-containing solvent, particularly preferably dioxane. The obtained polysilane has a high molecular mass and, at 100° C., a viscosity of 1,500 to 3,000 Pa·s. The polysilane is very suitable for being processed to form silicon carbide fibers and fiber composites.
High-molecular polysilane and method for the production thereof for producing pre-ceramic molded bodies
A method produces a polysilane by reacting at least two silane monomers and at least one alkali metal. The silane monomers have the following structural units: at least one aryl group, at least one alkyl group, at least one alkenyl group, and at least three halogen atoms. Wherein at least three of the halogen atoms are bonded to a silicon atom of one of the silane monomers, and the reaction step takes place in an ether-containing solvent, particularly preferably dioxane. The obtained polysilane has a high molecular mass and, at 100° C., a viscosity of 1,500 to 3,000 Pa·s. The polysilane is very suitable for being processed to form silicon carbide fibers and fiber composites.
High-molecular polysilane and method for the production thereof for producing pre-ceramic molded bodies
GRABE NORMAN (Autor:in)
12.02.2019
Patent
Elektronische Ressource
Englisch
IPC:
C08G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
,
Makromolekulare Verbindungen, anders erhalten als durch Reaktionen, an denen nur ungesättigte Kohlenstoff-Kohlenstoff-Bindungen beteiligt sind
/
B29C
Formen oder Verbinden von Kunststoffen
,
SHAPING OR JOINING OF PLASTICS
/
B29K
Index-Schema für Formmassen oder Materialien für Verstärkungen, Füllstoffe oder vorgeformte Teile, z.B. Einlagen in Verbindung mit den Unterklassen B29B, B29C oder B29D
,
INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
/
C01B
NON-METALLIC ELEMENTS
,
Nichtmetallische Elemente
/
C04B
Kalk
,
LIME
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