Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Kinetic and products study of the gas-phase reaction of Lewisite with ozone under atmospheric conditions
The rate constant for the gas-phase reaction of O3 and Lewisite was studied in air using the smog chamber technique. The experiments were carried out under pseudo-first-order reaction conditions with [O3]≪[Lewisite]. The observed rate constant of O3 with Lewisite was (7.83±0.38)×10(-19)cm(3)/(molecule·sec) at 298±2K. Lewisite was discussed in terms of reactivity with O3 and its relationship with the ionization potential. Our results show that the rate constant for the gas-phase reaction of O3 with Lewisite is in line with the trend of the rate constants of O3 with haloalkenes.
Kinetic and products study of the gas-phase reaction of Lewisite with ozone under atmospheric conditions
The rate constant for the gas-phase reaction of O3 and Lewisite was studied in air using the smog chamber technique. The experiments were carried out under pseudo-first-order reaction conditions with [O3]≪[Lewisite]. The observed rate constant of O3 with Lewisite was (7.83±0.38)×10(-19)cm(3)/(molecule·sec) at 298±2K. Lewisite was discussed in terms of reactivity with O3 and its relationship with the ionization potential. Our results show that the rate constant for the gas-phase reaction of O3 with Lewisite is in line with the trend of the rate constants of O3 with haloalkenes.
Kinetic and products study of the gas-phase reaction of Lewisite with ozone under atmospheric conditions
Wang, Haitao (Autor:in) / Zhang, Yuanpeng / Guo, Xiaodi / Shao, Yusheng / Gao, Runli / Liang, Dejian / Sun, Hao
2016
Aufsatz (Zeitschrift)
Englisch
Atomic-Absorption Determination of an Arsenic Impurity in Ammonium Chloride Derived from Lewisite
| British Library Online Contents | 1998