Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
The influence of hydrothermal synthesis conditions on gyrolite texture and specific surface area
Abstract Influence of hydrothermal synthesis conditions on the gyrolite specific surface area, dominant pore size and their differential distribution by the radius were determined. The synthesis of gyrolite has been carried out in unstirred suspensions within 32, 48, 72, 120, 168 h at 200°C temperature from a stoichiometric composition (the molar ratio of CaO/$ SiO_{2} $ was equal to 0.66 where water/solid ratio of the suspension was equal to 10.0) of the initial CaO and $ SiO_{2} $·n$ H_{2} $O mixture. It was found that the structure of gyrolite and the shape of dominated pores (from pores between parallel plates to cylindrical pores) changes prolonging the duration of hydrothermal synthesis. The stable gyrolite crystal lattice was formed only after 120 h of isothermal curing. Its specific surface area SBET = 38.28 $ m^{2} $/g, the radius of dominant plate pores rp = 30–40 Å, the cumulative pore volume ΣVp = 0.08 $ cm^{3} $/g. It was determined that the pores with 4.0–5.0 nm radius were dominated in gyrolite structure after 168 h of synthesis. It was estimated that the ion exchange between gyrolite with less orderly structure in Zn($ NO_{3} $)2 + $ NH_{4} $OH alkaline solution ($${c_{{{\text{Zn}}^{2+}}}}$$—0.3 g/$ dm^{3} $) proceeds more faster and effectively.
The influence of hydrothermal synthesis conditions on gyrolite texture and specific surface area
Abstract Influence of hydrothermal synthesis conditions on the gyrolite specific surface area, dominant pore size and their differential distribution by the radius were determined. The synthesis of gyrolite has been carried out in unstirred suspensions within 32, 48, 72, 120, 168 h at 200°C temperature from a stoichiometric composition (the molar ratio of CaO/$ SiO_{2} $ was equal to 0.66 where water/solid ratio of the suspension was equal to 10.0) of the initial CaO and $ SiO_{2} $·n$ H_{2} $O mixture. It was found that the structure of gyrolite and the shape of dominated pores (from pores between parallel plates to cylindrical pores) changes prolonging the duration of hydrothermal synthesis. The stable gyrolite crystal lattice was formed only after 120 h of isothermal curing. Its specific surface area SBET = 38.28 $ m^{2} $/g, the radius of dominant plate pores rp = 30–40 Å, the cumulative pore volume ΣVp = 0.08 $ cm^{3} $/g. It was determined that the pores with 4.0–5.0 nm radius were dominated in gyrolite structure after 168 h of synthesis. It was estimated that the ion exchange between gyrolite with less orderly structure in Zn($ NO_{3} $)2 + $ NH_{4} $OH alkaline solution ($${c_{{{\text{Zn}}^{2+}}}}$$—0.3 g/$ dm^{3} $) proceeds more faster and effectively.
The influence of hydrothermal synthesis conditions on gyrolite texture and specific surface area
Baltakys, K. (Autor:in) / Eisinas, A. (Autor:in) / Dizhbite, T. (Autor:in) / Jasina, L. (Autor:in) / Siauciunas, R. (Autor:in) / Kitrys, S. (Autor:in)
2011
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
The influence of hydrothermal synthesis conditions on gyrolite texture and specific surface area
| Online Contents | 2011
The influence of hydrothermal synthesis conditions on gyrolite texture and specific surface area
| British Library Online Contents | 2011
The influence of hydrothermal synthesis conditions on gyrolite texture and specific surface area
| Online Contents | 2011
The influence of hydrothermal synthesis conditions on gyrolite texture and specific surface area
| Springer Verlag | 2011
Formation of gyrolite from mixtures of CaO, SiO~2 and MgO under hydrothermal conditions
| British Library Online Contents | 1994