Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Thermogravimetric and Kinetic Analysis of Melon (Citrullus colocynthis L.) Seed Husk Using the Distributed Activation Energy Model
Abstract This study seeks to characterize the thermochemical fuel properties of melon seed husk (MSH) as a potential biomass feedstock for clean energy and power generation. It examined the ultimate analysis, proximate analysis, FTIR spectroscopy and thermal decomposition of MSH. Thermogravimetric (TG) analysis was examined at 5, 10, 20 °C/min from 30-800 °C under nitrogen atmosphere. Subsequently, the Distributed Activation Energy Model (DAEM) was applied to determine the activation energy, E, and frequency factor, A. The results revealed that thermal decomposition of MSH occurs in three (3) stages; drying (30-150 °C), devolatization (150-400 °C) and char degradation (400-800 °C). Kinetic analysis revealed that the E values fluctuated from 145.44-300 kJ/mol (Average E = 193 kJ/mol) while A ranged from 2.64 × $ 10^{10} $ to 9.18 × $ 10^{20} $ $ min^{-1} $ (Average E = 9.18 × $ 10^{19} $ $ min^{-1} $) highlighting the complexity of MSH pyrolysis. The fuel characterization and kinetics of MSH showed it is an environmentally friendly solid biofuel for future thermal biomass conversion.
Thermogravimetric and Kinetic Analysis of Melon (Citrullus colocynthis L.) Seed Husk Using the Distributed Activation Energy Model
Abstract This study seeks to characterize the thermochemical fuel properties of melon seed husk (MSH) as a potential biomass feedstock for clean energy and power generation. It examined the ultimate analysis, proximate analysis, FTIR spectroscopy and thermal decomposition of MSH. Thermogravimetric (TG) analysis was examined at 5, 10, 20 °C/min from 30-800 °C under nitrogen atmosphere. Subsequently, the Distributed Activation Energy Model (DAEM) was applied to determine the activation energy, E, and frequency factor, A. The results revealed that thermal decomposition of MSH occurs in three (3) stages; drying (30-150 °C), devolatization (150-400 °C) and char degradation (400-800 °C). Kinetic analysis revealed that the E values fluctuated from 145.44-300 kJ/mol (Average E = 193 kJ/mol) while A ranged from 2.64 × $ 10^{10} $ to 9.18 × $ 10^{20} $ $ min^{-1} $ (Average E = 9.18 × $ 10^{19} $ $ min^{-1} $) highlighting the complexity of MSH pyrolysis. The fuel characterization and kinetics of MSH showed it is an environmentally friendly solid biofuel for future thermal biomass conversion.
Thermogravimetric and Kinetic Analysis of Melon (Citrullus colocynthis L.) Seed Husk Using the Distributed Activation Energy Model
Nyakuma, Bemgba Bevan (Autor:in)
2015
Aufsatz (Zeitschrift)
Englisch
De-pulping and Seed Separation from Tumba (Citrullus colocynthis) Fruit
| Springer Verlag | 2017