Catalytic Decomposition of Methyl Formate in the Presence of Transition Metal Complexes, Phosphine Ligands and Water: Fid-Bau Portal

Catalytic Decomposition of Methyl Formate in the Presence of Transition Metal Complexes, Phosphine Ligands and Water

Gorbunov, D. N. / Semernina, V. A. / Terenina, M. V. / Kardasheva, Yu. S. / Maksimov, A. L. / Karakhanov, E. A.

Abstract The catalytic decomposition of methyl formate into gaseous components in the presence of transition metal complexes, phosphine ligands, and water has been studied. It has been shown that in the presence of monometallic and bimetallic Rh/Ru catalysts, methyl formate can be converted to gas mixtures with high hydrogen content. These mixtures are suitable for use in hydroformylation, hydroaminomethylation, and hydroformylation–acetalization reactions; therefore, methyl formate may be thought of as being an alternative source of synthesis gas in oxo processes.

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Catalytic Decomposition of Methyl Formate in the Presence of Transition Metal Complexes, Phosphine Ligands and Water

Gorbunov, D. N. / Semernina, V. A. / Terenina, M. V. / Kardasheva, Yu. S. / Maksimov, A. L. / Karakhanov, E. A.

Abstract

Catalytic Decomposition of Methyl Formate in the Presence of Transition Metal Complexes, Phosphine Ligands and Water

Gorbunov, D. N. / Semernina, V. A. / Terenina, M. V. / Kardasheva, Yu. S. / Maksimov, A. L. / Karakhanov, E. A.

Abstract

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Titel:

Catalytic Decomposition of Methyl Formate in the Presence of Transition Metal Complexes, Phosphine Ligands and Water

Beteiligte:

Gorbunov, D. N. (Autor:in) / Semernina, V. A. (Autor:in) / Terenina, M. V. (Autor:in) / Kardasheva, Yu. S. (Autor:in) / Maksimov, A. L. (Autor:in) / Karakhanov, E. A. (Autor:in)

Erschienen in:

Petroleum Chemistry ; 59 ; 412-419

Erscheinungsdatum:

01.04.2019

Format / Umfang:

8 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544119040078

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

methyl formate , synthesis gas , hydroformylation Chemistry , Industrial Chemistry/Chemical Engineering

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