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CoPMoV Sulfide Catalysts Supported on Natural Halloysite Nanotubes in Hydrotreating of Dibenzothiophene and Naphthalene
https://orcid.org/https://orcid.org/0000-0002-7827-7953
https://orcid.org/https://orcid.org/0000-0002-1373-2476
https://orcid.org/https://orcid.org/0009-0003-7110-8393
https://orcid.org/https://orcid.org/0000-0001-9712-3717
https://orcid.org/https://orcid.org/0000-0003-1578-5106
https://orcid.org/https://orcid.org/0000-0002-2877-0395
Mixed sulfided CoMo catalysts supported on γ-Al2O3 and halloysite nanotubes (HNTs) were synthesized by incipient wetness impregnation with salt solutions of Keggin-type phosphorus- and vanadium-containing heteropolyacids. The synthesized materials were characterized by low-temperature nitrogen adsorption, energy dispersive X-ray fluorescence analysis, temperature-programmed reduction (both for the oxide and sulfide catalysts), and Raman spectroscopy, and were tested in hydrogenation of naphthalene and hydrodesulfurization of dibenzothiophene. The HNT-supported catalyst exhibited a greater activity in these reactions.
CoPMoV Sulfide Catalysts Supported on Natural Halloysite Nanotubes in Hydrotreating of Dibenzothiophene and Naphthalene
https://orcid.org/https://orcid.org/0000-0002-7827-7953
https://orcid.org/https://orcid.org/0000-0002-1373-2476
https://orcid.org/https://orcid.org/0009-0003-7110-8393
https://orcid.org/https://orcid.org/0000-0001-9712-3717
https://orcid.org/https://orcid.org/0000-0003-1578-5106
https://orcid.org/https://orcid.org/0000-0002-2877-0395
Mixed sulfided CoMo catalysts supported on γ-Al2O3 and halloysite nanotubes (HNTs) were synthesized by incipient wetness impregnation with salt solutions of Keggin-type phosphorus- and vanadium-containing heteropolyacids. The synthesized materials were characterized by low-temperature nitrogen adsorption, energy dispersive X-ray fluorescence analysis, temperature-programmed reduction (both for the oxide and sulfide catalysts), and Raman spectroscopy, and were tested in hydrogenation of naphthalene and hydrodesulfurization of dibenzothiophene. The HNT-supported catalyst exhibited a greater activity in these reactions.
CoPMoV Sulfide Catalysts Supported on Natural Halloysite Nanotubes in Hydrotreating of Dibenzothiophene and Naphthalene
https://orcid.org/https://orcid.org/0000-0002-7827-7953
https://orcid.org/https://orcid.org/0000-0002-1373-2476
https://orcid.org/https://orcid.org/0009-0003-7110-8393
https://orcid.org/https://orcid.org/0000-0001-9712-3717
https://orcid.org/https://orcid.org/0000-0003-1578-5106
https://orcid.org/https://orcid.org/0000-0002-2877-0395
Mixed sulfided CoMo catalysts supported on γ-Al2O3 and halloysite nanotubes (HNTs) were synthesized by incipient wetness impregnation with salt solutions of Keggin-type phosphorus- and vanadium-containing heteropolyacids. The synthesized materials were characterized by low-temperature nitrogen adsorption, energy dispersive X-ray fluorescence analysis, temperature-programmed reduction (both for the oxide and sulfide catalysts), and Raman spectroscopy, and were tested in hydrogenation of naphthalene and hydrodesulfurization of dibenzothiophene. The HNT-supported catalyst exhibited a greater activity in these reactions.
CoPMoV Sulfide Catalysts Supported on Natural Halloysite Nanotubes in Hydrotreating of Dibenzothiophene and Naphthalene
Pet. Chem.
Vinogradov, N. A. (Autor:in) / Timoshkina, V. V. (Autor:in) / Tsilimbaeva, E. A. (Autor:in) / Zasypalov, G. O. (Autor:in) / Pimerzin, A. A. (Autor:in) / Glotov, A. P. (Autor:in)
Petroleum Chemistry ; 63 ; 931-938
01.08.2023
8 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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