Novel Strained Alicyclic Hydrocarbons Based on 5-Methylene-2-norbornene: Fid-Bau Portal

Fachinformationsdienst BAUdigital

Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik

Novel Strained Alicyclic Hydrocarbons Based on 5-Methylene-2-norbornene

Zarezin, D. P. / Rudakova, M. A. / Samoilov, V. O. / Sultanova, M. U. / Maximov, A. L. / Bermeshev, M. V.

The paper describes the synthesis of novel strained hydrocarbons based on a diene of the norbornene series, namely 5-methylene-2-norbornene, using catalytic cyclopropanation with diazomethane. The study demonstrated the possibility of selective cyclopropanation solely along the endocyclic double bond. The physicochemical properties of the hydrocarbons were investigated systematically. These hydrocarbons were shown to have an advantageous combination of high density, low freezing point, and high energy density value. The study’s findings indicate that the compounds synthesized are promising as a component of high-energy-density fuels for modern jet engines.

Zugriff

Seitennavigation

Dokumentinformationen

Ähnliche Titel

Exportieren, teilen und zitieren

Novel Strained Alicyclic Hydrocarbons Based on 5-Methylene-2-norbornene

Zarezin, D. P. / Rudakova, M. A. / Samoilov, V. O. / Sultanova, M. U. / Maximov, A. L. / Bermeshev, M. V.

The paper describes the synthesis of novel strained hydrocarbons based on a diene of the norbornene series, namely 5-methylene-2-norbornene, using catalytic cyclopropanation with diazomethane. The study demonstrated the possibility of selective cyclopropanation solely along the endocyclic double bond. The physicochemical properties of the hydrocarbons were investigated systematically. These hydrocarbons were shown to have an advantageous combination of high density, low freezing point, and high energy density value. The study’s findings indicate that the compounds synthesized are promising as a component of high-energy-density fuels for modern jet engines.

Novel Strained Alicyclic Hydrocarbons Based on 5-Methylene-2-norbornene

Zarezin, D. P. / Rudakova, M. A. / Samoilov, V. O. / Sultanova, M. U. / Maximov, A. L. / Bermeshev, M. V.

The paper describes the synthesis of novel strained hydrocarbons based on a diene of the norbornene series, namely 5-methylene-2-norbornene, using catalytic cyclopropanation with diazomethane. The study demonstrated the possibility of selective cyclopropanation solely along the endocyclic double bond. The physicochemical properties of the hydrocarbons were investigated systematically. These hydrocarbons were shown to have an advantageous combination of high density, low freezing point, and high energy density value. The study’s findings indicate that the compounds synthesized are promising as a component of high-energy-density fuels for modern jet engines.

Zugriff

Seitennavigation

Dokumentinformationen

Ähnliche Titel

Exportieren, teilen und zitieren

Dokumentinformationen

Titel:

Novel Strained Alicyclic Hydrocarbons Based on 5-Methylene-2-norbornene

Weitere Titelangaben:

Pet. Chem.

Beteiligte:

Zarezin, D. P. (Autor:in) / Rudakova, M. A. (Autor:in) / Samoilov, V. O. (Autor:in) / Sultanova, M. U. (Autor:in) / Maximov, A. L. (Autor:in) / Bermeshev, M. V. (Autor:in)

Erschienen in:

Petroleum Chemistry ; 61 ; 1033-1039

Erscheinungsdatum:

01.09.2021

Format / Umfang:

7 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544121090073

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

high-energy-density fuels , strained hydrocarbons , catalytic cyclopropanation , 5-methylene-2-norbornene Chemistry , Industrial Chemistry/Chemical Engineering , Chemistry and Materials Science

Lizenzbestimmungen:

http://creativecommons.org/licenses/by/4.0/

Ähnliche Titel

Erratum to: Novel Strained Alicyclic Hydrocarbons Based on 5-Methylene-2-norbornene

Zarezin, D. P. / Rudakova, M. A. / Samoilov, V. O. et al. | Springer Verlag | 2021

Copolymerization of 5-(trimethylsilyl)norbornene and 5-ethylidene-2-norbornene

Bulgakov, B. A. / Bermeshev, M. V. / Gringol’ts, M. L. et al. | Springer Verlag | 2012

Kinetic Model and Mechanism of Heterogeneous Hydrogenation of Strained Polycyclic Compounds Derived from 5-Vinyl-2-norbornene

Zamalyutin, V. V. / Katsman, E. A. / Flid, V. R. | Springer Verlag | 2023

Preparation of aliphatic and alicyclic tetracarboxylic acids

Rubinshtein, E.I. / Batalin, O.Ye. / Moldavskii, B.L. | Elsevier | 1970

Alternative methods for production of alicyclic epoxides

Vereshchagina, N. V. / Antonova, T. N. / Abramov, I. G. et al. | Springer Verlag | 2014