Cationic Oligomerization of the Pyrolysis C<Subscript>5</Subscript> Fraction: Fid-Bau Portal

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Cationic Oligomerization of the Pyrolysis C5 Fraction

Rozentsvet, V. A. / Kozlov, V. G. / Sablina, N. A. / Nesterov, V. N. / Fedorova, Z. D. / Munasypov, D. N. / Kiryukhin, A. M.

Abstract The cationic oligomerization of the pyrolysis C5 fraction in the presence of catalyst systems based on AlCl3, VOCl3, BF3 · O(C2H5)2, and a Gustavson complex has been investigated. It has been shown that the use of the diisopropyl ether-modified Gustavson complex in the reaction makes it possible to synthesize fully soluble oligomers in high yields. The conversions of all the unsaturated components of the pyrolysis fraction to the oligomer at different durations of the oligomerization process have been determined. The synthesized oligomers are characterized by high unsaturation and exhibit the properties of film-forming compounds.

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Cationic Oligomerization of the Pyrolysis C5 Fraction

Rozentsvet, V. A. / Kozlov, V. G. / Sablina, N. A. / Nesterov, V. N. / Fedorova, Z. D. / Munasypov, D. N. / Kiryukhin, A. M.

Abstract The cationic oligomerization of the pyrolysis C5 fraction in the presence of catalyst systems based on AlCl3, VOCl3, BF3 · O(C2H5)2, and a Gustavson complex has been investigated. It has been shown that the use of the diisopropyl ether-modified Gustavson complex in the reaction makes it possible to synthesize fully soluble oligomers in high yields. The conversions of all the unsaturated components of the pyrolysis fraction to the oligomer at different durations of the oligomerization process have been determined. The synthesized oligomers are characterized by high unsaturation and exhibit the properties of film-forming compounds.

Cationic Oligomerization of the Pyrolysis C5 Fraction

Rozentsvet, V. A. / Kozlov, V. G. / Sablina, N. A. / Nesterov, V. N. / Fedorova, Z. D. / Munasypov, D. N. / Kiryukhin, A. M.

Abstract The cationic oligomerization of the pyrolysis C5 fraction in the presence of catalyst systems based on AlCl3, VOCl3, BF3 · O(C2H5)2, and a Gustavson complex has been investigated. It has been shown that the use of the diisopropyl ether-modified Gustavson complex in the reaction makes it possible to synthesize fully soluble oligomers in high yields. The conversions of all the unsaturated components of the pyrolysis fraction to the oligomer at different durations of the oligomerization process have been determined. The synthesized oligomers are characterized by high unsaturation and exhibit the properties of film-forming compounds.

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Titel:

Cationic Oligomerization of the Pyrolysis C5 Fraction

Beteiligte:

Rozentsvet, V. A. (Autor:in) / Kozlov, V. G. (Autor:in) / Sablina, N. A. (Autor:in) / Nesterov, V. N. (Autor:in) / Fedorova, Z. D. (Autor:in) / Munasypov, D. N. (Autor:in) / Kiryukhin, A. M. (Autor:in)

Erschienen in:

Petroleum Chemistry ; 58 ; 694-701

Erscheinungsdatum:

17.07.2018

Format / Umfang:

8 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544118080200

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

pyrolysis fraction , cationic oligomerization , Gustavson complex , conversion of components , oligomer properties Chemistry , Industrial Chemistry/Chemical Engineering

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