Synthesis of Modified Catalyst for Liquid Phase Alkylation of Benzene with Ethylene: Fid-Bau Portal

Synthesis of Modified Catalyst for Liquid Phase Alkylation of Benzene with Ethylene

Shavaleev, D. A. / Pavlov, M. L. / Basimova, R. A. / Sadovnikov, A. A. / Sudin, V. V. / Smirnova, E. M. / Demikhova, N. R. / Grigor’ev, Yu. V. / Maksimov, A. L. / Naranov, E. R.

Abstract

Highly efficient binder-free catalysts, based on zeolite Y, for the liquid-phase alkylation of benzene with ethylene have been synthesized. The catalysts have been modified by treating with aqueous solutions of hydrochloric and citric acids to remove extra-framework aluminum formed during the partial dealumination of zeolite Y. The synthesized catalysts have been tested in the alkylation of benzene with ethylene at a temperature of 200°C, a pressure of 2.5 MPa, a benzene : ethylene molar ratio of 5 : 1, and a benzene feed space velocity of 5 h⁻¹. Over the modified catalyst, the ethylbenzene (EB) content in the alkylate increases by 27% and the EB selectivity increases by 5% compared to the initial Y zeolite.

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Synthesis of Modified Catalyst for Liquid Phase Alkylation of Benzene with Ethylene

Shavaleev, D. A. / Pavlov, M. L. / Basimova, R. A. / Sadovnikov, A. A. / Sudin, V. V. / Smirnova, E. M. / Demikhova, N. R. / Grigor’ev, Yu. V. / Maksimov, A. L. / Naranov, E. R.

Abstract

Synthesis of Modified Catalyst for Liquid Phase Alkylation of Benzene with Ethylene

Shavaleev, D. A. / Pavlov, M. L. / Basimova, R. A. / Sadovnikov, A. A. / Sudin, V. V. / Smirnova, E. M. / Demikhova, N. R. / Grigor’ev, Yu. V. / Maksimov, A. L. / Naranov, E. R.