Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
The influence of organic additives on the regioselectivity of oxygenation of alkanes with hydrogen peroxide in the presence of TS-1titanium silicalite
Abstract Hydrogen peroxide oxidizes n-hexane, n-heptane, and n-octane at 50°C in the presence titanium silicalite TS-1 as a catalyst, forming isomeric mixtures of ketones and alcohols. Admixtures of organic acids, alcohols, benzene, and ethylbenzene sharply change the ratio of position isomers. For example, the normalized ratio is C(4): C(3): C(2) = 0.44: 1.0: 0.47 for n-heptane oxidation in the absence of additives, but it becomes 0.52: 1.0: 1.00 in the presence of benzyl alcohol and the addition of ethylbenzene changes it to 0.16: 1.0: 0.94.
The influence of organic additives on the regioselectivity of oxygenation of alkanes with hydrogen peroxide in the presence of TS-1titanium silicalite
Abstract Hydrogen peroxide oxidizes n-hexane, n-heptane, and n-octane at 50°C in the presence titanium silicalite TS-1 as a catalyst, forming isomeric mixtures of ketones and alcohols. Admixtures of organic acids, alcohols, benzene, and ethylbenzene sharply change the ratio of position isomers. For example, the normalized ratio is C(4): C(3): C(2) = 0.44: 1.0: 0.47 for n-heptane oxidation in the absence of additives, but it becomes 0.52: 1.0: 1.00 in the presence of benzyl alcohol and the addition of ethylbenzene changes it to 0.16: 1.0: 0.94.
The influence of organic additives on the regioselectivity of oxygenation of alkanes with hydrogen peroxide in the presence of TS-1titanium silicalite
Shul’pin, G. B. (Autor:in) / Sooknoi, T. (Autor:in) / Shul’pina, L. S. (Autor:in)
Petroleum Chemistry ; 48 ; 36-39
01.01.2008
4 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
Biochar-surface oxygenation with hydrogen peroxide
| Online Contents | 2016
| British Library Online Contents | 1998
The Corrosion Behavior of Titanium in Hydrogen Peroxide Solution with Various Additives
| British Library Online Contents | 2007
Oxidation of organic sulfur compounds with hydrogen peroxide in the presence of crown ethers
| Springer Verlag | 2007