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Effects of Synthesis Method on the Localization of Aluminum Atoms and on Catalytic Performance of BEA Zeolite in Toluene Disproportionation
https://orcid.org/https://orcid.org/0000-0002-3435-2878
https://orcid.org/https://orcid.org/0000-0001-5634-6690
https://orcid.org/https://orcid.org/0000-0001-8095-6923
https://orcid.org/https://orcid.org/0009-0003-1091-5562
https://orcid.org/https://orcid.org/0009-0002-0335-4819
https://orcid.org/https://orcid.org/0000-0002-7882-5833
https://orcid.org/https://orcid.org/0000-0002-8742-2892
The physicochemical properties of BEA zeolites with SiO2/Al2O3 ratios of about 40–50 and 200–250 synthesized in fluoride and alkaline media have been characterized, and their catalytic activity have been tested in liquid-phase disproportionation of toluene. It has been found that samples with a close SiO2/Al2O3 ratio obtained by fluoride synthesis have a smaller number of acid sites. The samples with lower SiO2/Al2O3 ratios exhibite a higher activity in toluene disproportionation than the samples with lower Al content, regardless of the synthesis method. The BEA zeolites that have Al atoms in the T6 positions of the framework which are more active. Synthesis in an alkaline medium promotes the localization of aluminum at the T6 position.
Effects of Synthesis Method on the Localization of Aluminum Atoms and on Catalytic Performance of BEA Zeolite in Toluene Disproportionation
https://orcid.org/https://orcid.org/0000-0002-3435-2878
https://orcid.org/https://orcid.org/0000-0001-5634-6690
https://orcid.org/https://orcid.org/0000-0001-8095-6923
https://orcid.org/https://orcid.org/0009-0003-1091-5562
https://orcid.org/https://orcid.org/0009-0002-0335-4819
https://orcid.org/https://orcid.org/0000-0002-7882-5833
https://orcid.org/https://orcid.org/0000-0002-8742-2892
The physicochemical properties of BEA zeolites with SiO2/Al2O3 ratios of about 40–50 and 200–250 synthesized in fluoride and alkaline media have been characterized, and their catalytic activity have been tested in liquid-phase disproportionation of toluene. It has been found that samples with a close SiO2/Al2O3 ratio obtained by fluoride synthesis have a smaller number of acid sites. The samples with lower SiO2/Al2O3 ratios exhibite a higher activity in toluene disproportionation than the samples with lower Al content, regardless of the synthesis method. The BEA zeolites that have Al atoms in the T6 positions of the framework which are more active. Synthesis in an alkaline medium promotes the localization of aluminum at the T6 position.
Effects of Synthesis Method on the Localization of Aluminum Atoms and on Catalytic Performance of BEA Zeolite in Toluene Disproportionation
https://orcid.org/https://orcid.org/0000-0002-3435-2878
https://orcid.org/https://orcid.org/0000-0001-5634-6690
https://orcid.org/https://orcid.org/0000-0001-8095-6923
https://orcid.org/https://orcid.org/0009-0003-1091-5562
https://orcid.org/https://orcid.org/0009-0002-0335-4819
https://orcid.org/https://orcid.org/0000-0002-7882-5833
https://orcid.org/https://orcid.org/0000-0002-8742-2892
The physicochemical properties of BEA zeolites with SiO2/Al2O3 ratios of about 40–50 and 200–250 synthesized in fluoride and alkaline media have been characterized, and their catalytic activity have been tested in liquid-phase disproportionation of toluene. It has been found that samples with a close SiO2/Al2O3 ratio obtained by fluoride synthesis have a smaller number of acid sites. The samples with lower SiO2/Al2O3 ratios exhibite a higher activity in toluene disproportionation than the samples with lower Al content, regardless of the synthesis method. The BEA zeolites that have Al atoms in the T6 positions of the framework which are more active. Synthesis in an alkaline medium promotes the localization of aluminum at the T6 position.
Effects of Synthesis Method on the Localization of Aluminum Atoms and on Catalytic Performance of BEA Zeolite in Toluene Disproportionation
Pet. Chem.
Kostyukov, I. A. (Autor:in) / Ponomareva, O. A. (Autor:in) / Kolyagin, Yu. G. (Autor:in) / Petz, M. I. (Autor:in) / Shutkina, O. V. (Autor:in) / Bok, T. O. (Autor:in) / Ivanova, I. I. (Autor:in)
Petroleum Chemistry ; 64 ; 202-209
01.02.2024
8 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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