Synthesis, Characterization, and Applications of Substituted Polyacetylenes Derived from Ring-Opening Metathesis Polymerization of Cyclooctatetraenes: Fid-Bau Portal

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Synthesis, Characterization, and Applications of Substituted Polyacetylenes Derived from Ring-Opening Metathesis Polymerization of Cyclooctatetraenes

Ginsburg, E. J. / Gorman, C. B. / Grubbs, R. H. / Klavetter, F. L. / Lewis, N. S. / Marder, S. R. / Perry, J. W. / Sailor, M. J.

Abstract Polyacetylene and partially substituted derivatives of polyacetylene are synthesized via the ring-opening metathesis polymerization (ROMP) of cyclooctatetraene (COT) and its derivatives. The physical properties and characterization of these polymers are reported. In particular, certain poly-COT derivatives afford soluble, highly conjugated polyacetylenes. Nonlinear optical properties are highlighted by the fact that, in several cases, scattering losses are greatly minimized. These polymers have also been used in device applications such as Schottky barrier diodes and solar cells.

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Synthesis, Characterization, and Applications of Substituted Polyacetylenes Derived from Ring-Opening Metathesis Polymerization of Cyclooctatetraenes

Ginsburg, E. J. / Gorman, C. B. / Grubbs, R. H. / Klavetter, F. L. / Lewis, N. S. / Marder, S. R. / Perry, J. W. / Sailor, M. J.

Abstract Polyacetylene and partially substituted derivatives of polyacetylene are synthesized via the ring-opening metathesis polymerization (ROMP) of cyclooctatetraene (COT) and its derivatives. The physical properties and characterization of these polymers are reported. In particular, certain poly-COT derivatives afford soluble, highly conjugated polyacetylenes. Nonlinear optical properties are highlighted by the fact that, in several cases, scattering losses are greatly minimized. These polymers have also been used in device applications such as Schottky barrier diodes and solar cells.

Synthesis, Characterization, and Applications of Substituted Polyacetylenes Derived from Ring-Opening Metathesis Polymerization of Cyclooctatetraenes

Ginsburg, E. J. / Gorman, C. B. / Grubbs, R. H. / Klavetter, F. L. / Lewis, N. S. / Marder, S. R. / Perry, J. W. / Sailor, M. J.

Abstract Polyacetylene and partially substituted derivatives of polyacetylene are synthesized via the ring-opening metathesis polymerization (ROMP) of cyclooctatetraene (COT) and its derivatives. The physical properties and characterization of these polymers are reported. In particular, certain poly-COT derivatives afford soluble, highly conjugated polyacetylenes. Nonlinear optical properties are highlighted by the fact that, in several cases, scattering losses are greatly minimized. These polymers have also been used in device applications such as Schottky barrier diodes and solar cells.

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Titel:

Synthesis, Characterization, and Applications of Substituted Polyacetylenes Derived from Ring-Opening Metathesis Polymerization of Cyclooctatetraenes

Beteiligte:

Ginsburg, E. J. (Autor:in) / Gorman, C. B. (Autor:in) / Grubbs, R. H. (Autor:in) / Klavetter, F. L. (Autor:in) / Lewis, N. S. (Autor:in) / Marder, S. R. (Autor:in) / Perry, J. W. (Autor:in) / Sailor, M. J. (Autor:in)

Erschienen in:

Conjugated Polymeric Materials: Opportunities in Electronics, Optoelectronics, and Molecular Electronics ; 65-81

NATO ASI Series ; 182

Erscheinungsdatum:

01.01.1990

Format / Umfang:

17 pages

ISBN:

978-94-010-7416-2 , 978-94-009-2041-5

ISSN:

DOI:

https://doi.org/10.1007/978-94-009-2041-5_4

Medientyp:

Aufsatz/Kapitel (Buch)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

Solar Cell , Block Copolymer , Nonlinear Optical Property , Third Harmonic Generation , Conjugation Length Chemistry , Industrial Chemistry/Chemical Engineering , Characterization and Evaluation of Materials , Organic Chemistry , Optics, Lasers, Photonics, Optical Devices

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