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Physicochemical Properties and Catalytic Performance of MEL Zeolites Synthesized by Steam-Assisted Conversion
https://orcid.org/https://orcid.org/0000-0003-3226-3537
https://orcid.org/https://orcid.org/0000-0002-6900-8516
https://orcid.org/https://orcid.org/0000-0002-8742-2892
MEL-type zeolite was synthesized by a novel steam-assisted crystallization method. This zeolite was characterized by X-ray diffraction, low-temperature nitrogen adsorption/desorption, scanning electron microscopy, and X-ray fluorescence analysis. IR spectroscopy of probe molecules (pyridine and 2,6-di-tert-butylpyridine) was used to characterize the acidic properties of this sample. The MEL zeolite synthesized by steam-assisted crystallization consisted of aggregated nanocrystals up to 300 nm in size and exhibited a high phase purity, a large micropore volume (0.13 cm3/g), and high concentrations of both Brønsted and Lewis acid sites. When tested in oligomerization of a butane–butylene fraction and hydroconversion of n-hexadecane, this MEL zeolite proved to be comparable to MFI-type zeolites in terms of catalytic performance.
Physicochemical Properties and Catalytic Performance of MEL Zeolites Synthesized by Steam-Assisted Conversion
https://orcid.org/https://orcid.org/0000-0003-3226-3537
https://orcid.org/https://orcid.org/0000-0002-6900-8516
https://orcid.org/https://orcid.org/0000-0002-8742-2892
MEL-type zeolite was synthesized by a novel steam-assisted crystallization method. This zeolite was characterized by X-ray diffraction, low-temperature nitrogen adsorption/desorption, scanning electron microscopy, and X-ray fluorescence analysis. IR spectroscopy of probe molecules (pyridine and 2,6-di-tert-butylpyridine) was used to characterize the acidic properties of this sample. The MEL zeolite synthesized by steam-assisted crystallization consisted of aggregated nanocrystals up to 300 nm in size and exhibited a high phase purity, a large micropore volume (0.13 cm3/g), and high concentrations of both Brønsted and Lewis acid sites. When tested in oligomerization of a butane–butylene fraction and hydroconversion of n-hexadecane, this MEL zeolite proved to be comparable to MFI-type zeolites in terms of catalytic performance.
Physicochemical Properties and Catalytic Performance of MEL Zeolites Synthesized by Steam-Assisted Conversion
https://orcid.org/https://orcid.org/0000-0003-3226-3537
https://orcid.org/https://orcid.org/0000-0002-6900-8516
https://orcid.org/https://orcid.org/0000-0002-8742-2892
MEL-type zeolite was synthesized by a novel steam-assisted crystallization method. This zeolite was characterized by X-ray diffraction, low-temperature nitrogen adsorption/desorption, scanning electron microscopy, and X-ray fluorescence analysis. IR spectroscopy of probe molecules (pyridine and 2,6-di-tert-butylpyridine) was used to characterize the acidic properties of this sample. The MEL zeolite synthesized by steam-assisted crystallization consisted of aggregated nanocrystals up to 300 nm in size and exhibited a high phase purity, a large micropore volume (0.13 cm3/g), and high concentrations of both Brønsted and Lewis acid sites. When tested in oligomerization of a butane–butylene fraction and hydroconversion of n-hexadecane, this MEL zeolite proved to be comparable to MFI-type zeolites in terms of catalytic performance.
Physicochemical Properties and Catalytic Performance of MEL Zeolites Synthesized by Steam-Assisted Conversion
Pet. Chem.
Artamonova, V. A. (Autor:in) / Popov, A. G. (Autor:in) / Ivanova, I. I. (Autor:in)
Petroleum Chemistry ; 63 ; 699-707
01.07.2023
9 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
Physicochemical and catalytic properties of iron- and indium-containing zeolites
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Catalytic conversion of n-butenes on zeolites
| Elsevier | 1973
| British Library Online Contents | 2013