Hydroxycarbonylation of isobutylene in the presence of the palladium acetylacetonate-triphenylphosphine-<Emphasis Type="Italic">p</Emphasis>-toluenesulfonic acid catalyst system: Fid-Bau Portal

Hydroxycarbonylation of isobutylene in the presence of the palladium acetylacetonate-triphenylphosphine-p-toluenesulfonic acid catalyst system

Suerbaev, Kh. A. / Chepaikin, E. G. / Zhaksylykova, G. Zh. / Kanybetov, K. S. / Turkbenov, T. K. / Abyzbekova, G. M.

Abstract

Abstract The reaction of isobutylene hydroxycarbonylation with carbon monoxide and an alcohol (ethanol, 1-menthol) in the presence of the palladium acetylacetonate-triphenylphosphine-p-toluenesulfonic acid catalytic system was investigated. It was shown that the reaction proceeds regioselectively with the formation of linear products (ethyl isovalerate, 1-menthyl isovalerate). The optimum conditions for running the process were found, at which the yield of the main products is 67–79%.

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Hydroxycarbonylation of isobutylene in the presence of the palladium acetylacetonate-triphenylphosphine-p-toluenesulfonic acid catalyst system

Suerbaev, Kh. A. / Chepaikin, E. G. / Zhaksylykova, G. Zh. / Kanybetov, K. S. / Turkbenov, T. K. / Abyzbekova, G. M.

Abstract

Hydroxycarbonylation of isobutylene in the presence of the palladium acetylacetonate-triphenylphosphine-p-toluenesulfonic acid catalyst system

Suerbaev, Kh. A. / Chepaikin, E. G. / Zhaksylykova, G. Zh. / Kanybetov, K. S. / Turkbenov, T. K. / Abyzbekova, G. M.

Abstract

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Titel:

Hydroxycarbonylation of isobutylene in the presence of the palladium acetylacetonate-triphenylphosphine-p-toluenesulfonic acid catalyst system

Beteiligte:

Suerbaev, Kh. A. (Autor:in) / Chepaikin, E. G. (Autor:in) / Zhaksylykova, G. Zh. (Autor:in) / Kanybetov, K. S. (Autor:in) / Turkbenov, T. K. (Autor:in) / Abyzbekova, G. M. (Autor:in)

Erschienen in:

Petroleum Chemistry ; 48 ; 206-209

Erscheinungsdatum:

01.05.2008

Format / Umfang:

4 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544108030067

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

Acac , Isobutylene , Menthol , Petroleum Chemistry , TsOH Chemistry , Industrial Chemistry/Chemical Engineering

Suerbaev, Kh. A. / Chepaikin, E. G. / Zhaksylykova, G. Zh. | Springer Verlag | 2012

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Suerbaev, H. A. / Chepajkin, E. G. / Dzhiembaev, B. Zh. et al. | Springer Verlag | 2007

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Guang, L. / Weigui, G. / Shaoping, P. | British Library Online Contents | 2006

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