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Catalytic aminomethylation of alkenes in a dimethylformamide medium

Karakhanov, E. A. / Runova, E. A. / Kardasheva, Yu. S. / Losev, D. V. / Maksimov, A. L. / Terenina, M. V.

Abstract The hydroaminomethylation of alkenes with dimethylamine catalyzed by rhodium and ruthenium complexes in a dimethylformamide medium under synthesis-gas pressures of 2 MPa has been studied. It has been shown that the combined use of these metals leads to a significant increase in the rate of formation of amines and selectivity for n-alkyldimethylamine. It has been found that the reaction can proceed with dimethylformamide used as an aminating agent without the addition of dimethylamine.

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Catalytic aminomethylation of alkenes in a dimethylformamide medium

Karakhanov, E. A. / Runova, E. A. / Kardasheva, Yu. S. / Losev, D. V. / Maksimov, A. L. / Terenina, M. V.

Abstract The hydroaminomethylation of alkenes with dimethylamine catalyzed by rhodium and ruthenium complexes in a dimethylformamide medium under synthesis-gas pressures of 2 MPa has been studied. It has been shown that the combined use of these metals leads to a significant increase in the rate of formation of amines and selectivity for n-alkyldimethylamine. It has been found that the reaction can proceed with dimethylformamide used as an aminating agent without the addition of dimethylamine.

Catalytic aminomethylation of alkenes in a dimethylformamide medium

Karakhanov, E. A. / Runova, E. A. / Kardasheva, Yu. S. / Losev, D. V. / Maksimov, A. L. / Terenina, M. V.

Abstract The hydroaminomethylation of alkenes with dimethylamine catalyzed by rhodium and ruthenium complexes in a dimethylformamide medium under synthesis-gas pressures of 2 MPa has been studied. It has been shown that the combined use of these metals leads to a significant increase in the rate of formation of amines and selectivity for n-alkyldimethylamine. It has been found that the reaction can proceed with dimethylformamide used as an aminating agent without the addition of dimethylamine.

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Titel:

Catalytic aminomethylation of alkenes in a dimethylformamide medium

Beteiligte:

Karakhanov, E. A. (Autor:in) / Runova, E. A. (Autor:in) / Kardasheva, Yu. S. (Autor:in) / Losev, D. V. (Autor:in) / Maksimov, A. L. (Autor:in) / Terenina, M. V. (Autor:in)

Erschienen in:

Petroleum Chemistry ; 52 ; 179-185

Erscheinungsdatum:

01.05.2012

Format / Umfang:

7 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S096554411203005X

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

Acac , Rhodium , Petroleum Chemistry , Catalyst System , Enamine Chemistry , Industrial Chemistry/Chemical Engineering

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