Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
The Effect of Sulfonate Groups in the Structure of Porous Aromatic Frameworks on the Activity of Platinum Catalysts Towards Hydrodeoxygenation of Biofuel Components
https://orcid.org/https://orcid.org/0000-0002-2157-0227
https://orcid.org/https://orcid.org/0000-0002-7665-5404
https://orcid.org/https://orcid.org/0000-0002-1868-8232
https://orcid.org/https://orcid.org/0000-0001-9297-4950
https://orcid.org/https://orcid.org/0000-0003-4727-954X
Platinum catalysts based on porous aromatic frameworks (PAF-30 and PAF-30–SO3H) have been synthesized. Properties of the obtained catalysts have been assessed via hydrogenation of guaiacol, veratrole, and pyrocatechol at 250°С and hydrogen pressure 3.0 MPa in isopropanol medium. It has been shown that the presence of acidic sites in the catalyst significantly increases the yield of deoxygenation products. The effect of the substrate structure on the rate of its hydrodeoxygenation and the mechanism of the occurring processes have been studied.
The Effect of Sulfonate Groups in the Structure of Porous Aromatic Frameworks on the Activity of Platinum Catalysts Towards Hydrodeoxygenation of Biofuel Components
https://orcid.org/https://orcid.org/0000-0002-2157-0227
https://orcid.org/https://orcid.org/0000-0002-7665-5404
https://orcid.org/https://orcid.org/0000-0002-1868-8232
https://orcid.org/https://orcid.org/0000-0001-9297-4950
https://orcid.org/https://orcid.org/0000-0003-4727-954X
Platinum catalysts based on porous aromatic frameworks (PAF-30 and PAF-30–SO3H) have been synthesized. Properties of the obtained catalysts have been assessed via hydrogenation of guaiacol, veratrole, and pyrocatechol at 250°С and hydrogen pressure 3.0 MPa in isopropanol medium. It has been shown that the presence of acidic sites in the catalyst significantly increases the yield of deoxygenation products. The effect of the substrate structure on the rate of its hydrodeoxygenation and the mechanism of the occurring processes have been studied.
The Effect of Sulfonate Groups in the Structure of Porous Aromatic Frameworks on the Activity of Platinum Catalysts Towards Hydrodeoxygenation of Biofuel Components
https://orcid.org/https://orcid.org/0000-0002-2157-0227
https://orcid.org/https://orcid.org/0000-0002-7665-5404
https://orcid.org/https://orcid.org/0000-0002-1868-8232
https://orcid.org/https://orcid.org/0000-0001-9297-4950
https://orcid.org/https://orcid.org/0000-0003-4727-954X
Platinum catalysts based on porous aromatic frameworks (PAF-30 and PAF-30–SO3H) have been synthesized. Properties of the obtained catalysts have been assessed via hydrogenation of guaiacol, veratrole, and pyrocatechol at 250°С and hydrogen pressure 3.0 MPa in isopropanol medium. It has been shown that the presence of acidic sites in the catalyst significantly increases the yield of deoxygenation products. The effect of the substrate structure on the rate of its hydrodeoxygenation and the mechanism of the occurring processes have been studied.
The Effect of Sulfonate Groups in the Structure of Porous Aromatic Frameworks on the Activity of Platinum Catalysts Towards Hydrodeoxygenation of Biofuel Components
Pet. Chem.
Kalinina, M. A. (Autor:in) / Kulikov, L. A. (Autor:in) / Cherednichenko, K. A. (Autor:in) / Maximov, A. L. (Autor:in) / Karakhanov, E. A. (Autor:in)
Petroleum Chemistry ; 61 ; 1061-1070
01.09.2021
10 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
Hydrogenation of Lignin Bio-Oil Components over Catalysts Based on Porous Aromatic Frameworks
| Springer Verlag | 2022
Cyclohexene Epoxidation Catalysts Based on Porous Aromatic Frameworks
| Springer Verlag | 2020
Molybdenum Catalysts Supported on Porous Aromatic Frameworks in Epoxidation of Olefins
| Springer Verlag | 2024
Hydrogenation of Furfural over Ruthenium Catalysts Supported on Porous Aromatic Frameworks
| Springer Verlag | 2024