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Catalytic hydrogenation of dicyclopentadiene to dicyclopentene in the liquid phase
Abstract A new use for dicyclopentadiene has been proposed in the area of preparation of oxygen-containing compounds, including those with a cage structure, the key stage of which is the selective liquid-phase hydrogenation of dicyclopentadiene to dicyclopentene with hydrogen over finely divided hydrogenation catalysts based on platinum group metals. The process proceeds under mild conditions at atmospheric pressure. Conditions providing a yield of 92% for the desired product with an almost complete conversion of the reactant dicyclopentadiene have been determined in the study of the hydrogenation reaction in both a volumetric device of the closed type and a continuous-flow system.
Catalytic hydrogenation of dicyclopentadiene to dicyclopentene in the liquid phase
Abstract A new use for dicyclopentadiene has been proposed in the area of preparation of oxygen-containing compounds, including those with a cage structure, the key stage of which is the selective liquid-phase hydrogenation of dicyclopentadiene to dicyclopentene with hydrogen over finely divided hydrogenation catalysts based on platinum group metals. The process proceeds under mild conditions at atmospheric pressure. Conditions providing a yield of 92% for the desired product with an almost complete conversion of the reactant dicyclopentadiene have been determined in the study of the hydrogenation reaction in both a volumetric device of the closed type and a continuous-flow system.
Catalytic hydrogenation of dicyclopentadiene to dicyclopentene in the liquid phase
Antonova, T. N. (Autor:in) / Abramov, I. A. (Autor:in) / Feldblyum, V. Sh. (Autor:in) / Abramov, I. G. (Autor:in) / Danilova, A. S. (Autor:in)
Petroleum Chemistry ; 49 ; 366-368
01.09.2009
3 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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