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Direct Catalytic Oxidation of Propane: Effects of Inhibitors
https://orcid.org/https://orcid.org/0000-0002-1631-021X
https://orcid.org/https://orcid.org/0000-0003-3128-0837
https://orcid.org/https://orcid.org/0000-0001-8200-0706
This study investigated the effects of ionol (2,6-di-tert-butyl-4-methylphenol) and CCl4 as inhibitors of radical reactions in propane oxidation with oxygen in the presence of co-reductants. These compounds inhibit the activity of a Pd/C–FeSO4–H2 catalytic system. Homogeneous catalytic systems based on Pd or Rh compounds, cocatalysts, and co-reductants promote molecular mechanisms for the reaction. The only exception is a Pd(α,α-bipy)Cl2–FeSO4–CO system, in which both ionol and CCl4 act as inhibitors.
Direct Catalytic Oxidation of Propane: Effects of Inhibitors
https://orcid.org/https://orcid.org/0000-0002-1631-021X
https://orcid.org/https://orcid.org/0000-0003-3128-0837
https://orcid.org/https://orcid.org/0000-0001-8200-0706
This study investigated the effects of ionol (2,6-di-tert-butyl-4-methylphenol) and CCl4 as inhibitors of radical reactions in propane oxidation with oxygen in the presence of co-reductants. These compounds inhibit the activity of a Pd/C–FeSO4–H2 catalytic system. Homogeneous catalytic systems based on Pd or Rh compounds, cocatalysts, and co-reductants promote molecular mechanisms for the reaction. The only exception is a Pd(α,α-bipy)Cl2–FeSO4–CO system, in which both ionol and CCl4 act as inhibitors.
Direct Catalytic Oxidation of Propane: Effects of Inhibitors
https://orcid.org/https://orcid.org/0000-0002-1631-021X
https://orcid.org/https://orcid.org/0000-0003-3128-0837
https://orcid.org/https://orcid.org/0000-0001-8200-0706
This study investigated the effects of ionol (2,6-di-tert-butyl-4-methylphenol) and CCl4 as inhibitors of radical reactions in propane oxidation with oxygen in the presence of co-reductants. These compounds inhibit the activity of a Pd/C–FeSO4–H2 catalytic system. Homogeneous catalytic systems based on Pd or Rh compounds, cocatalysts, and co-reductants promote molecular mechanisms for the reaction. The only exception is a Pd(α,α-bipy)Cl2–FeSO4–CO system, in which both ionol and CCl4 act as inhibitors.
Direct Catalytic Oxidation of Propane: Effects of Inhibitors
Pet. Chem.
Chepaikin, E. G. (Autor:in) / Menchikova, G. N. (Autor:in) / Pomogailo, S. I. (Autor:in)
Petroleum Chemistry ; 62 ; 654-659
01.06.2022
6 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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