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Chemistry of Dimethyl Ether: Catalytic Synthesis of 1,3-Butadiene
Abstract Catalytic synthesis of 1,3-butadiene from dimethyl ether (DME) has been carried out for the first time. It has been established that 1,3-butadiene forms via three possible routes of reactions between DME conversion products: by reaction of propylene with formaldehyde according to the Prins condensation mechanism, by DME isomerization of to ethanol followed by its conversion to 1,3-butadiene through acetaldehyde, and by dehydrogenation of butylenes.
Chemistry of Dimethyl Ether: Catalytic Synthesis of 1,3-Butadiene
Abstract Catalytic synthesis of 1,3-butadiene from dimethyl ether (DME) has been carried out for the first time. It has been established that 1,3-butadiene forms via three possible routes of reactions between DME conversion products: by reaction of propylene with formaldehyde according to the Prins condensation mechanism, by DME isomerization of to ethanol followed by its conversion to 1,3-butadiene through acetaldehyde, and by dehydrogenation of butylenes.
Chemistry of Dimethyl Ether: Catalytic Synthesis of 1,3-Butadiene
Khadzhiev, S. N. (Autor:in) / Maksimov, A. L. (Autor:in) / Tret’yakov, V. F. (Autor:in) / Talyshinskii, R. M. (Autor:in) / Ilolov, A. M. (Autor:in)
Petroleum Chemistry ; 58 ; 613-621
17.07.2018
9 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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