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High-Vinyl Polybutadiene Crosslinked in the Strained State to Different Degrees of Crosslinking

Batsberg, W. / Hvidt, S. / Kramer, O. / Fetters, L. J.

Abstract It is demonstrated that chain entangling in a well crosslinked polybutadiene network results in an equilibrium elastic contribution, which equals the rubber plateau modulus of the same uncrosslinked polymer. It is found to be true for crosslink densities varying by as much as a factor of four. This result is obtained by introducing the crosslinks in the strained state. No theory and no assumptions are required.

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High-Vinyl Polybutadiene Crosslinked in the Strained State to Different Degrees of Crosslinking

Batsberg, W. / Hvidt, S. / Kramer, O. / Fetters, L. J.

Abstract It is demonstrated that chain entangling in a well crosslinked polybutadiene network results in an equilibrium elastic contribution, which equals the rubber plateau modulus of the same uncrosslinked polymer. It is found to be true for crosslink densities varying by as much as a factor of four. This result is obtained by introducing the crosslinks in the strained state. No theory and no assumptions are required.

High-Vinyl Polybutadiene Crosslinked in the Strained State to Different Degrees of Crosslinking

Batsberg, W. / Hvidt, S. / Kramer, O. / Fetters, L. J.

Abstract It is demonstrated that chain entangling in a well crosslinked polybutadiene network results in an equilibrium elastic contribution, which equals the rubber plateau modulus of the same uncrosslinked polymer. It is found to be true for crosslink densities varying by as much as a factor of four. This result is obtained by introducing the crosslinks in the strained state. No theory and no assumptions are required.

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Titel:

High-Vinyl Polybutadiene Crosslinked in the Strained State to Different Degrees of Crosslinking

Beteiligte:

Batsberg, W. (Autor:in) / Hvidt, S. (Autor:in) / Kramer, O. (Autor:in) / Fetters, L. J. (Autor:in)

Erschienen in:

Biological and Synthetic Polymer Networks ; 509-516

Erscheinungsdatum:

01.01.1988

Format / Umfang:

8 pages

ISBN:

978-94-010-7097-3 , 978-94-009-1343-1

DOI:

https://doi.org/10.1007/978-94-009-1343-1_35

Medientyp:

Aufsatz/Kapitel (Buch)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

Stress Relaxation , Chain Scission , Equilibrium Force , Anionic Polymerization , Rubber Elasticity Chemistry , Industrial Chemistry/Chemical Engineering , Characterization and Evaluation of Materials , Polymer Sciences

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