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Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Alkali activation of mechanically activated low-grade clay
This article reports the results of an investigation into the efficiency of mechanical activation to increase the reactivity in alkali activated mortar synthesized from low-grade clay. Mechanical activation significantly changed the structure of clay, increasing the specific surface area, and decreasing the particle size. The 7-day compressive strength of mortar synthesized from untreated clay was 31.7 MPa, which increased to 35.3 after 4 h milling. A further increase of grinding time to 8 h did not result in any increase in compressive strength which is attributed to a decrease in the workability. However, the extent of reactivity did significantly increase as determined from solid-state MAS NMR, FTIR, and EDS analyses. Solid-state MAS NMR results revealed the increased formation of Q4(2Al) silicon sites, which is correlated with improved reaction. Furthermore, the EDS and FTIR analysis results indicated greater incorporation of aluminium into the matrix structure with increased grinding time.
Alkali activation of mechanically activated low-grade clay
This article reports the results of an investigation into the efficiency of mechanical activation to increase the reactivity in alkali activated mortar synthesized from low-grade clay. Mechanical activation significantly changed the structure of clay, increasing the specific surface area, and decreasing the particle size. The 7-day compressive strength of mortar synthesized from untreated clay was 31.7 MPa, which increased to 35.3 after 4 h milling. A further increase of grinding time to 8 h did not result in any increase in compressive strength which is attributed to a decrease in the workability. However, the extent of reactivity did significantly increase as determined from solid-state MAS NMR, FTIR, and EDS analyses. Solid-state MAS NMR results revealed the increased formation of Q4(2Al) silicon sites, which is correlated with improved reaction. Furthermore, the EDS and FTIR analysis results indicated greater incorporation of aluminium into the matrix structure with increased grinding time.
Alkali activation of mechanically activated low-grade clay
Yamchelou, Morteza Tahmasebi (Autor:in) / Law, David W. (Autor:in) / Patnaikuni, Indubushan (Autor:in) / Li, Jie (Autor:in)
Journal of Sustainable Cement-Based Materials ; 10 ; 272-288
16.08.2021
17 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Unbekannt
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