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Sol-gel template synthesis of visible photoactive Cu-S co-doped mesoporous TiO2 catalyst
A new visible photoactive catalyst (Cu, S/PEG-PVA/TiO2) was synthesized by the sol-gel method. In addition, Cu, S/TiO2 and Bare TiO2 were synthesized to compare their properties and activities. The synthesized catalysts were characterized using XRD, N2 adsorption–desorption measurements, SEM, TEM, EDX, UV-Vis spectroscopy and TGA. The photocatalytic activities of the synthesized photocatalysts were evaluated by measuring the photocatalytic degradation of 4-nitrophenol under visible light irradiation. Then, the impacts of three parameters, (catalyst loading, pH and H2O2 concentration) for optimization and modelization of the 4-nitrophenol photodegradation were studied using the response surface methodology. Optimal conditions obtained from statistical analysis at a catalyst loading of 1 gL−1, pH of 3.98 and H2O2 concentration of 8 mg/L have shown the highest 4-NP percentage degradation of 70.5% in 1 h. The results predicted by the models were found to be in good agreement with those obtained by performing the experiment (R 2 = 0.9443 and Adj-R 2 = 0.9038).
Sol-gel template synthesis of visible photoactive Cu-S co-doped mesoporous TiO2 catalyst
A new visible photoactive catalyst (Cu, S/PEG-PVA/TiO2) was synthesized by the sol-gel method. In addition, Cu, S/TiO2 and Bare TiO2 were synthesized to compare their properties and activities. The synthesized catalysts were characterized using XRD, N2 adsorption–desorption measurements, SEM, TEM, EDX, UV-Vis spectroscopy and TGA. The photocatalytic activities of the synthesized photocatalysts were evaluated by measuring the photocatalytic degradation of 4-nitrophenol under visible light irradiation. Then, the impacts of three parameters, (catalyst loading, pH and H2O2 concentration) for optimization and modelization of the 4-nitrophenol photodegradation were studied using the response surface methodology. Optimal conditions obtained from statistical analysis at a catalyst loading of 1 gL−1, pH of 3.98 and H2O2 concentration of 8 mg/L have shown the highest 4-NP percentage degradation of 70.5% in 1 h. The results predicted by the models were found to be in good agreement with those obtained by performing the experiment (R 2 = 0.9443 and Adj-R 2 = 0.9038).
Sol-gel template synthesis of visible photoactive Cu-S co-doped mesoporous TiO2 catalyst
Hamisu, Abubakar (Autor:in) / Bala, Sani Saminu (Autor:in) / Bello, Abdu Muhammad (Autor:in) / Abubakar, Abdullahi Musa (Autor:in) / Adeyi, Abel Adekanmi (Autor:in)
Journal of Applied Water Engineering and Research ; 11 ; 357-369
03.07.2023
13 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Unbekannt
Sol-gel , Bi-template , Cu-S codoped , mesoporous TiO2 , RSM
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