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Modifications to the Sunset Laboratory Carbon Aerosol Monitor for the Simultaneous Measurement of PM2.5 Nonvolatile and Semi-Volatile Carbonaceous Material
Semi-volatile organic carbonaceous material (SVOC) in fine particles is not reliably measured with conventional semicontinuous carbon monitors because semi-volatile carbonaceous material is lost from the collection media during sample collection. Two modifications of a Sunset Laboratory carbon aerosol monitor allowing for the determination of semi-volatile fine particulate organic material are described. Collocated conventional and modified instruments were operated simultaneously using a common inlet. Comparisons were made with integrated PC-BOSS data for quartz filter retained nonvolatile organic carbon (NVOC) and elemental carbon (EC), SVOC, and total carbon (TC = SVOC + NVOC + EC) and good agreement was observed between TC concentrations during studies conducted in Rubidoux, CA. Precision of the comparison was σ=±1.5 μg-C/m3 (±8%). On the basis of experiments performed with the modified Sunset monitor, a dual-oven Sunset monitor was developed and extensively tested in Lindon, UT; Riverside, CA; and in environmental exposure chambers. The precision for the measurement of TC with the dual-oven instrument was σ = ±1.4 μg-C/m3 (±13%).
Modifications to the Sunset Laboratory Carbon Aerosol Monitor for the Simultaneous Measurement of PM2.5 Nonvolatile and Semi-Volatile Carbonaceous Material
Semi-volatile organic carbonaceous material (SVOC) in fine particles is not reliably measured with conventional semicontinuous carbon monitors because semi-volatile carbonaceous material is lost from the collection media during sample collection. Two modifications of a Sunset Laboratory carbon aerosol monitor allowing for the determination of semi-volatile fine particulate organic material are described. Collocated conventional and modified instruments were operated simultaneously using a common inlet. Comparisons were made with integrated PC-BOSS data for quartz filter retained nonvolatile organic carbon (NVOC) and elemental carbon (EC), SVOC, and total carbon (TC = SVOC + NVOC + EC) and good agreement was observed between TC concentrations during studies conducted in Rubidoux, CA. Precision of the comparison was σ=±1.5 μg-C/m3 (±8%). On the basis of experiments performed with the modified Sunset monitor, a dual-oven Sunset monitor was developed and extensively tested in Lindon, UT; Riverside, CA; and in environmental exposure chambers. The precision for the measurement of TC with the dual-oven instrument was σ = ±1.4 μg-C/m3 (±13%).
Modifications to the Sunset Laboratory Carbon Aerosol Monitor for the Simultaneous Measurement of PM2.5 Nonvolatile and Semi-Volatile Carbonaceous Material
Grover, Brett D. (Autor:in) / Eatough, Norman L. (Autor:in) / Woolwine, Woods R. (Autor:in) / Eatough, Delbert J. (Autor:in) / Cary, Robert A. (Autor:in)
Journal of the Air & Waste Management Association ; 59 ; 1007-1017
01.08.2009
11 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Unbekannt
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