Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Factors affecting lead release in sodium silicate-treated partial lead service line replacements
Water quality parameters affecting sodium silicate performance in partial lead service line replacements were examined using a fractional factorial experimental design and static pipe systems. An external copper wire was used to create a galvanic connection between a former lead service line and a new copper pipe. The pipe systems were filled with lab prepared water made to mimic real water quality. Water was changed on a three times per week basis. A 24−1 fractional factorial design was used to evaluate the impact of alkalinity (15 mg L−1 or 250 mg L−1 as CaCO3), nitrate (1 mg L−1 or 7 mg L−1 as N), natural organic matter (1 mg L−1 or 7 mg L−1 as dissolved organic carbon), and disinfectant type (1 mg L−1 chlorine or 3 mg L−1 monochloramine), resulting in eight treatment conditions. Fractional factorial analysis revealed that alkalinity, natural organic matter and monochloramine had a significant positive effect on galvanic current. Natural organic matter and monochloramine also had a significant positive effect with respect to both total and dissolved lead release. For the treatment conditions examined, 67–98% of the lead released through galvanic currents was stored as corrosion scales and predominantly comprised of particulate lead (96.1–99.9%) for all eight treatments. The use of monochloramine and the presence of natural organic matter (7 mg L−1) were not favourable for corrosion control in sodium silicate-treated partial lead service line replacements, although further studies would be required to characterize optimal water quality parameters for specific water quality types. For utilities operating with sodium silicate as a corrosion inhibitor, this work offers further evidence regarding the consideration of chlorine as a secondary disinfectant instead of monochloramine, as well as the value of controlling natural organic matter in distributed water.
Factors affecting lead release in sodium silicate-treated partial lead service line replacements
Water quality parameters affecting sodium silicate performance in partial lead service line replacements were examined using a fractional factorial experimental design and static pipe systems. An external copper wire was used to create a galvanic connection between a former lead service line and a new copper pipe. The pipe systems were filled with lab prepared water made to mimic real water quality. Water was changed on a three times per week basis. A 24−1 fractional factorial design was used to evaluate the impact of alkalinity (15 mg L−1 or 250 mg L−1 as CaCO3), nitrate (1 mg L−1 or 7 mg L−1 as N), natural organic matter (1 mg L−1 or 7 mg L−1 as dissolved organic carbon), and disinfectant type (1 mg L−1 chlorine or 3 mg L−1 monochloramine), resulting in eight treatment conditions. Fractional factorial analysis revealed that alkalinity, natural organic matter and monochloramine had a significant positive effect on galvanic current. Natural organic matter and monochloramine also had a significant positive effect with respect to both total and dissolved lead release. For the treatment conditions examined, 67–98% of the lead released through galvanic currents was stored as corrosion scales and predominantly comprised of particulate lead (96.1–99.9%) for all eight treatments. The use of monochloramine and the presence of natural organic matter (7 mg L−1) were not favourable for corrosion control in sodium silicate-treated partial lead service line replacements, although further studies would be required to characterize optimal water quality parameters for specific water quality types. For utilities operating with sodium silicate as a corrosion inhibitor, this work offers further evidence regarding the consideration of chlorine as a secondary disinfectant instead of monochloramine, as well as the value of controlling natural organic matter in distributed water.
Factors affecting lead release in sodium silicate-treated partial lead service line replacements
Zhou, Emily (Autor:in) / Payne, Sarah Jane O. (Autor:in) / Hofmann, Ron (Autor:in) / Andrews, Robert C. (Autor:in)
Journal of Environmental Science and Health, Part A ; 50 ; 922-930
29.07.2015
9 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
Factors affecting lead release in sodium silicate-treated partial lead service line replacements
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