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Hydrothermal transformation of the calcium aluminum oxide hydrates CaAl2O4 dot 10H2O and Ca2Al 2O5 dot 8H2O to Ca3Al 2(OH)12 investigated by in situ synchrotron X-ray powder diffraction
The hydrothermal transformation of calcium aluminate hydrates were investigated by in situ synchrotron X-ray powder diffraction in the temperature range 25 to 170 degree C. This technique allowed the study of the detailed reaction mechanism and identification of intermediate phases. The material CaAl2O4*10H2O converted to Ca 3Al2(OH)12 and amorphous aluminum hydroxide. Ca2Al2 O5*8H2O transformed via the intermediate phase Ca4 Al2O7*13H 2O to Ca3Al2(OH)12 and gibbsite, Al(OH)3. The phase Ca4Al2O 7*19H2O reacted via the same intermediate phase to Ca3Al2(OH)12 and mainly amorphous aluminum hydroxide. The powder pattern of the intermediate phase is reported.
Hydrothermal transformation of the calcium aluminum oxide hydrates CaAl2O4 dot 10H2O and Ca2Al 2O5 dot 8H2O to Ca3Al 2(OH)12 investigated by in situ synchrotron X-ray powder diffraction
The hydrothermal transformation of calcium aluminate hydrates were investigated by in situ synchrotron X-ray powder diffraction in the temperature range 25 to 170 degree C. This technique allowed the study of the detailed reaction mechanism and identification of intermediate phases. The material CaAl2O4*10H2O converted to Ca 3Al2(OH)12 and amorphous aluminum hydroxide. Ca2Al2 O5*8H2O transformed via the intermediate phase Ca4 Al2O7*13H 2O to Ca3Al2(OH)12 and gibbsite, Al(OH)3. The phase Ca4Al2O 7*19H2O reacted via the same intermediate phase to Ca3Al2(OH)12 and mainly amorphous aluminum hydroxide. The powder pattern of the intermediate phase is reported.
Hydrothermal transformation of the calcium aluminum oxide hydrates CaAl2O4 dot 10H2O and Ca2Al 2O5 dot 8H2O to Ca3Al 2(OH)12 investigated by in situ synchrotron X-ray powder diffraction
Jensen, Torben R. (Autor:in) / Christensen, Axel Norlund (Autor:in) / Hanson, Jonathan C. (Autor:in)
Cement and Concrete Research ; 35 ; 2300-2309
2005
10 Seiten, 22 Quellen
Aufsatz (Zeitschrift)
Englisch
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