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Impact of organic matter constituents on phosphorus recovery from CPR sludges
AbstractThis study evaluated the influence of organic matter (OM) constituents on the potential for recovery of P from wastewaters when FeCl3 treatment is employed for P removal. The presence of OM constituents did not influence P release from Fe‐P sludges when alkaline and ascorbic acid treatments were employed. However, the overall recovery of P from wastewater was impacted by the presence of selected OM constituents through the reduction of P uptake during coagulation. The presence of protein and humic matter showed remarkably low P removal values (3.0 ± 0.4% and 23 ± 1% respectively) when compared to an inorganic control recipe (62 ± 2%). Elevated soluble Fe (SFe) residuals in the presence of proteins (87 ± 5%) and humics (51 ± 1%) indicated interactions between Fe(III) cations and negatively charged functional groups like hydroxyl, carboxyl, and phenolic groups available in these organics. Significant negative correlations between P removal and residual SFe were observed suggesting Fe solubilization by OM constituents was the mechanism responsible for reduced P removal. The findings of this study identify, for the first time, the impact of OM constituents on overall P recovery when Fe(III) salts are employed and provide insights into recoveries that can be expected when Fe is added to primary, secondary treated, and industrial wastewaters.Practitioner Points Low P removal values were observed for protein and humic dominated wastewater recipes. Iron(III) solubilization counted for P removal reduction by proteins and humic acids. There is no effect of OM on P release from Fe‐P sludge at pH 10 and ascorbic acid treatments. OM and agent employed to release P from sludges affected overall recovery of P.
Impact of organic matter constituents on phosphorus recovery from CPR sludges
AbstractThis study evaluated the influence of organic matter (OM) constituents on the potential for recovery of P from wastewaters when FeCl3 treatment is employed for P removal. The presence of OM constituents did not influence P release from Fe‐P sludges when alkaline and ascorbic acid treatments were employed. However, the overall recovery of P from wastewater was impacted by the presence of selected OM constituents through the reduction of P uptake during coagulation. The presence of protein and humic matter showed remarkably low P removal values (3.0 ± 0.4% and 23 ± 1% respectively) when compared to an inorganic control recipe (62 ± 2%). Elevated soluble Fe (SFe) residuals in the presence of proteins (87 ± 5%) and humics (51 ± 1%) indicated interactions between Fe(III) cations and negatively charged functional groups like hydroxyl, carboxyl, and phenolic groups available in these organics. Significant negative correlations between P removal and residual SFe were observed suggesting Fe solubilization by OM constituents was the mechanism responsible for reduced P removal. The findings of this study identify, for the first time, the impact of OM constituents on overall P recovery when Fe(III) salts are employed and provide insights into recoveries that can be expected when Fe is added to primary, secondary treated, and industrial wastewaters.Practitioner Points Low P removal values were observed for protein and humic dominated wastewater recipes. Iron(III) solubilization counted for P removal reduction by proteins and humic acids. There is no effect of OM on P release from Fe‐P sludge at pH 10 and ascorbic acid treatments. OM and agent employed to release P from sludges affected overall recovery of P.
Impact of organic matter constituents on phosphorus recovery from CPR sludges
Water Environment Research
Alnimer, Aseel A. (Autor:in) / Smith, D. Scott (Autor:in) / Parker, Wayne J. (Autor:in)
01.10.2024
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch