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Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
Sterically highly crowded and twisted thienylene‐phenylenes are synthesized and structurally characterized. Single‐crystal X‐ray structure analyses and theoretical studies give evidence of through‐space delocalization of π‐electrons of peripheral (hetero)aromatic rings in toroidal and catenated topology.
Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
Sterically highly crowded and twisted thienylene‐phenylenes are synthesized and structurally characterized. Single‐crystal X‐ray structure analyses and theoretical studies give evidence of through‐space delocalization of π‐electrons of peripheral (hetero)aromatic rings in toroidal and catenated topology.
Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
Leitner, Tanja Desirée (Autor:in) / von Glasenapp, Jan Simon (Autor:in) / Herges, Rainer (Autor:in) / Mena‐Osteritz, Elena (Autor:in) / Bäuerle, Peter (Autor:in)
Advanced Science ; 9
01.07.2022
10 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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