Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Kinetic Investigation Exploiting Local Parameter Subset Selection: Isomerization of 1‐Decene using a Rh‐Biphephos Catalyst
A kinetic study of the isomerization of 1‐decene using a Rh‐Biphephos catalyst was performed in order to parameterize a mechanistic kinetic model to observed experimental data. For the derivation of the kinetic model, a previously proposed catalytic cycle was revised regarding the catalyst pre‐equilibrium including the formation of inactive or non‐selective Rh‐species. In order to estimate the model parameters and to support model reduction, a method based on parameter subset selection was extended and applied. Using this approach, sensitive kinetic parameters were identified and determined for the reduced kinetic model.
Kinetic Investigation Exploiting Local Parameter Subset Selection: Isomerization of 1‐Decene using a Rh‐Biphephos Catalyst
A kinetic study of the isomerization of 1‐decene using a Rh‐Biphephos catalyst was performed in order to parameterize a mechanistic kinetic model to observed experimental data. For the derivation of the kinetic model, a previously proposed catalytic cycle was revised regarding the catalyst pre‐equilibrium including the formation of inactive or non‐selective Rh‐species. In order to estimate the model parameters and to support model reduction, a method based on parameter subset selection was extended and applied. Using this approach, sensitive kinetic parameters were identified and determined for the reduced kinetic model.
Kinetic Investigation Exploiting Local Parameter Subset Selection: Isomerization of 1‐Decene using a Rh‐Biphephos Catalyst
Jörke, Andreas (Autor:in) / Triemer, Susann (Autor:in) / Seidel‐Morgenstern, Andreas (Autor:in) / Hamel, Christof (Autor:in)
Chemie Ingenieur Technik ; 87 ; 713-725
01.06.2015
13 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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