Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Reduction of 2,4‐Dinitrotoluene with Graphite and Titanium Mesh Cathodes
Electrochemical degradation of 2,4‐dinitrotoluene (DNT) in a bench‐scale reactor was studied, and a number of parameters including dissolved oxygen, current, voltage, and electrode shape and material were investigated. Quantified rates of degradation ranged from 0.003 to 0.008 min−1 for graphite and 0.003 to 0.06 min−1 for titanium. Products of degradation were identified as diaminotoluene (DAT) and azoxy dimers and, in some cases, were also quantified. An azoxy dimer was found only in experiments with dissolved oxygen, and regioselectivity favoring the first reduction at the para position was evident based on product studies. Degradation studies using a graphite rod cathode were mass‐transfer limited, while degradation studies using titanium mesh wire were not. The material of the electrode had a strong influence on degradation rates and on the way that different water quality parameters affect the rate of 2,4‐DNT degradation.
Reduction of 2,4‐Dinitrotoluene with Graphite and Titanium Mesh Cathodes
Electrochemical degradation of 2,4‐dinitrotoluene (DNT) in a bench‐scale reactor was studied, and a number of parameters including dissolved oxygen, current, voltage, and electrode shape and material were investigated. Quantified rates of degradation ranged from 0.003 to 0.008 min−1 for graphite and 0.003 to 0.06 min−1 for titanium. Products of degradation were identified as diaminotoluene (DAT) and azoxy dimers and, in some cases, were also quantified. An azoxy dimer was found only in experiments with dissolved oxygen, and regioselectivity favoring the first reduction at the para position was evident based on product studies. Degradation studies using a graphite rod cathode were mass‐transfer limited, while degradation studies using titanium mesh wire were not. The material of the electrode had a strong influence on degradation rates and on the way that different water quality parameters affect the rate of 2,4‐DNT degradation.
Reduction of 2,4‐Dinitrotoluene with Graphite and Titanium Mesh Cathodes
Jolas, J.L. (Autor:in) / Pehkonen, S.O. (Autor:in) / Maloney, S.W. (Autor:in)
Water Environment Research ; 72 ; 179-188
01.03.2000
10 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
VI. 2-Amino-4,6-Dinitrotoluene
Online Contents | 1999
Ozone reaction with 2,4-dinitrotoluene in acetic acid solution
| British Library Online Contents | 2004
Abiotic reduction of 2,4-dinitrotoluene in the presence of sulfide minerals under anoxic conditions
| British Library Conference Proceedings | 1996
Biodegradation of 2,4-Dinitrotoluene (DNT) under Anaerobic Condition
| British Library Online Contents | 2002
VI. 2-Amino-4,6-Dinitrotoluene - B. Aquatic Toxicology
Online Contents | 1999